Chenxin Ye , Xinyao Wang , Junliang Zhang , Boping Li , Jiancheng Yu
{"title":"低压空气介质阻挡放电等离子体电离源实验研究","authors":"Chenxin Ye , Xinyao Wang , Junliang Zhang , Boping Li , Jiancheng Yu","doi":"10.1016/j.ijms.2025.117493","DOIUrl":null,"url":null,"abstract":"<div><div>This study experimentally investigates the properties of low-pressure dielectric barrier discharge (DBD) plasma. A ring-ring DBD configuration was employed. Spectroscopic and electrical measurements were conducted at varying gas pressures to characterize the plasma properties. The results revealed that the luminous region of the plasma expands and exhibits maximum luminescence near 600 Pa, with a subsequent contraction and intensity diminution at lower pressures. Analysis of emission spectra identified nitrogen's second positive system (SPS) and first negative system (FNS) as the primary contributors. The highest density of excited molecule <span><math><mrow><msub><mi>N</mi><mn>2</mn></msub><mrow><mo>(</mo><mrow><msup><mi>C</mi><mn>3</mn></msup><msub><mi>Π</mi><mi>u</mi></msub></mrow><mo>)</mo></mrow></mrow></math></span> and excited ion <span><math><mrow><msubsup><mi>N</mi><mn>2</mn><mo>+</mo></msubsup><mrow><mo>(</mo><mrow><msup><mi>B</mi><mn>2</mn></msup><msubsup><mi>Σ</mi><mi>u</mi><mo>+</mo></msubsup></mrow><mo>)</mo></mrow></mrow></math></span> are at 660 Pa and 100 Pa, respectively. Mass spectrometry measurements indicate that the excited state <span><math><mrow><msub><mi>N</mi><mn>2</mn></msub><mrow><mo>(</mo><mrow><msup><mi>C</mi><mn>3</mn></msup><msub><mi>Π</mi><mi>u</mi></msub></mrow><mo>)</mo></mrow></mrow></math></span> has the ability to undergo Penning ionization. This study provides the variation of excited molecules and ions with pressure in low-pressure dielectric barrier discharge, which can be used for the optimization of ionization source and the analysis of mass spectrometry data.</div></div>","PeriodicalId":338,"journal":{"name":"International Journal of Mass Spectrometry","volume":"516 ","pages":"Article 117493"},"PeriodicalIF":1.6000,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental studies on low-pressure air dielectric barrier discharge plasma for ionization source\",\"authors\":\"Chenxin Ye , Xinyao Wang , Junliang Zhang , Boping Li , Jiancheng Yu\",\"doi\":\"10.1016/j.ijms.2025.117493\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study experimentally investigates the properties of low-pressure dielectric barrier discharge (DBD) plasma. A ring-ring DBD configuration was employed. Spectroscopic and electrical measurements were conducted at varying gas pressures to characterize the plasma properties. The results revealed that the luminous region of the plasma expands and exhibits maximum luminescence near 600 Pa, with a subsequent contraction and intensity diminution at lower pressures. Analysis of emission spectra identified nitrogen's second positive system (SPS) and first negative system (FNS) as the primary contributors. The highest density of excited molecule <span><math><mrow><msub><mi>N</mi><mn>2</mn></msub><mrow><mo>(</mo><mrow><msup><mi>C</mi><mn>3</mn></msup><msub><mi>Π</mi><mi>u</mi></msub></mrow><mo>)</mo></mrow></mrow></math></span> and excited ion <span><math><mrow><msubsup><mi>N</mi><mn>2</mn><mo>+</mo></msubsup><mrow><mo>(</mo><mrow><msup><mi>B</mi><mn>2</mn></msup><msubsup><mi>Σ</mi><mi>u</mi><mo>+</mo></msubsup></mrow><mo>)</mo></mrow></mrow></math></span> are at 660 Pa and 100 Pa, respectively. Mass spectrometry measurements indicate that the excited state <span><math><mrow><msub><mi>N</mi><mn>2</mn></msub><mrow><mo>(</mo><mrow><msup><mi>C</mi><mn>3</mn></msup><msub><mi>Π</mi><mi>u</mi></msub></mrow><mo>)</mo></mrow></mrow></math></span> has the ability to undergo Penning ionization. This study provides the variation of excited molecules and ions with pressure in low-pressure dielectric barrier discharge, which can be used for the optimization of ionization source and the analysis of mass spectrometry data.</div></div>\",\"PeriodicalId\":338,\"journal\":{\"name\":\"International Journal of Mass Spectrometry\",\"volume\":\"516 \",\"pages\":\"Article 117493\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-07-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387380625000971\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387380625000971","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Experimental studies on low-pressure air dielectric barrier discharge plasma for ionization source
This study experimentally investigates the properties of low-pressure dielectric barrier discharge (DBD) plasma. A ring-ring DBD configuration was employed. Spectroscopic and electrical measurements were conducted at varying gas pressures to characterize the plasma properties. The results revealed that the luminous region of the plasma expands and exhibits maximum luminescence near 600 Pa, with a subsequent contraction and intensity diminution at lower pressures. Analysis of emission spectra identified nitrogen's second positive system (SPS) and first negative system (FNS) as the primary contributors. The highest density of excited molecule and excited ion are at 660 Pa and 100 Pa, respectively. Mass spectrometry measurements indicate that the excited state has the ability to undergo Penning ionization. This study provides the variation of excited molecules and ions with pressure in low-pressure dielectric barrier discharge, which can be used for the optimization of ionization source and the analysis of mass spectrometry data.
期刊介绍:
The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics.
Papers, in which standard mass spectrometry techniques are used for analysis will not be considered.
IJMS publishes full-length articles, short communications, reviews, and feature articles including young scientist features.