Dean-Kawasaki方程与随机密度泛函理论。

IF 20.7
Pierre Illien
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引用次数: 0

摘要

Dean-Kawasaki (DK)方程是在随机密度泛函数理论(SDFT)的基础上提出的,用于描述相互作用的布朗粒子的密度演变,它可以代表大量的系统,如胶体悬浮液、过冷液体、聚合物熔体、生物分子、活性或趋化粒子或溶液中的离子。这个理论框架可以概括为控制粒子动力学的耦合过阻尼朗之万方程的数学重新表述,在过去三十年中引起了大量的关注。在这篇综述中,我介绍了引入该框架的背景,并回顾了用于推导DK方程的主要假设和计算技术。然后,在更广泛的统计力学背景下,我展示了SDFT如何与其他理论联系起来,如波动流体力学、宏观波动理论或模式耦合理论。由DK方程提出的数学问题以非专业语言呈现。在回顾的最后部分,我展示了如何在几个方向上扩展原始结果,我提出了用于解析和数值求解DK方程的不同策略和近似。我最后列出了SDFT用于描述布朗悬浮液波动的不同情况,从活性物质的物理学到带电粒子和电解质的描述。 。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Dean-Kawasaki equation and stochastic density functional theory.

The Dean-Kawasaki (DK) equation, which is at the basis of stochastic density functional theory (SDFT), was proposed in the mid-nineties to describe the evolution of the density of interacting Brownian particles, which can represent a large number of systems such as colloidal suspensions, supercooled liquids, polymer melts, biological molecules, active or chemotactic particles, or ions in solution. This theoretical framework, which can be summarized as a mathematical reformulation of the coupled overdamped Langevin equations that govern the dynamics of the particles, has attracted a significant amount of attention during the past thirty years. In this review, I present the context in which this framework was introduced, and I recall the main assumptions and calculation techniques that are employed to derive the DK equation. Then, in the broader context of statistical mechanics, I show how SDFT is connected to other theories, such fluctuating hydrodynamics, macroscopic fluctuation theory, or mode-coupling theory. The mathematical questions that are raised by the DK equation are presented in a non-specialist language. In the last parts of the review, I show how the original result was extended in several directions, I present the different strategies and approximations that have been employed to solve the DK equation, both analytically and numerically. I finally list the different situations where SDFT was employed to describe the fluctuations of Brownian suspensions, from the physics of active matter to the description of charged particles and electrolytes.

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