{"title":"粒径控制TiO2纳米颗粒的电流变流体性能研究。","authors":"Seongjin Kim, Hyukjoon Gwon, Seungae Lee","doi":"10.1002/cplu.202500317","DOIUrl":null,"url":null,"abstract":"<p><p>Electrorheological (ER) fluids, known for their tunable viscosity under electric fields, are of significant interest for various engineering applications, including shock absorbers and haptic feedback systems. This study investigates the impact of size-controlled TiO2 nanoparticles on the performance of ER fluids. TiO2 nanoparticles with diameters ranging from 143 to 370 nm were synthesized using a double-surfactant assembly-directed method. Rheological measurements revealed that ER fluids containing smaller TiO2 particles exhibited higher shear stress under an electric field. Additionally, optical microscopy confirmed that smaller spheres formed denser fibrillar structures, thereby enhancing ER fluid performance. However, dielectric property analysis showed that smaller particles had lower polarizability and slower relaxation. Sedimentation tests indicated that ER fluids with smaller TiO2 particles had improved dispersion stability, further enhancing the performance of the ER fluid. These findings provide valuable insights into optimizing ER fluid performance by controlling TiO2 particle size.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":" ","pages":"e202500317"},"PeriodicalIF":2.8000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of Electrorheological Fluid Performance with Size-Controlled TiO2 Nanoparticles.\",\"authors\":\"Seongjin Kim, Hyukjoon Gwon, Seungae Lee\",\"doi\":\"10.1002/cplu.202500317\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Electrorheological (ER) fluids, known for their tunable viscosity under electric fields, are of significant interest for various engineering applications, including shock absorbers and haptic feedback systems. This study investigates the impact of size-controlled TiO2 nanoparticles on the performance of ER fluids. TiO2 nanoparticles with diameters ranging from 143 to 370 nm were synthesized using a double-surfactant assembly-directed method. Rheological measurements revealed that ER fluids containing smaller TiO2 particles exhibited higher shear stress under an electric field. Additionally, optical microscopy confirmed that smaller spheres formed denser fibrillar structures, thereby enhancing ER fluid performance. However, dielectric property analysis showed that smaller particles had lower polarizability and slower relaxation. Sedimentation tests indicated that ER fluids with smaller TiO2 particles had improved dispersion stability, further enhancing the performance of the ER fluid. These findings provide valuable insights into optimizing ER fluid performance by controlling TiO2 particle size.</p>\",\"PeriodicalId\":148,\"journal\":{\"name\":\"ChemPlusChem\",\"volume\":\" \",\"pages\":\"e202500317\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemPlusChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/cplu.202500317\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemPlusChem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cplu.202500317","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Investigation of Electrorheological Fluid Performance with Size-Controlled TiO2 Nanoparticles.
Electrorheological (ER) fluids, known for their tunable viscosity under electric fields, are of significant interest for various engineering applications, including shock absorbers and haptic feedback systems. This study investigates the impact of size-controlled TiO2 nanoparticles on the performance of ER fluids. TiO2 nanoparticles with diameters ranging from 143 to 370 nm were synthesized using a double-surfactant assembly-directed method. Rheological measurements revealed that ER fluids containing smaller TiO2 particles exhibited higher shear stress under an electric field. Additionally, optical microscopy confirmed that smaller spheres formed denser fibrillar structures, thereby enhancing ER fluid performance. However, dielectric property analysis showed that smaller particles had lower polarizability and slower relaxation. Sedimentation tests indicated that ER fluids with smaller TiO2 particles had improved dispersion stability, further enhancing the performance of the ER fluid. These findings provide valuable insights into optimizing ER fluid performance by controlling TiO2 particle size.
期刊介绍:
ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.