具有16-MR通道的磷酸镁草酸盐具有超高的质子电导率。

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-07-10 DOI:10.1039/D5DT00576K

Xin Shao, Xin Wang, Wei Zhao, Liangliang Huang and Yanfeng Bi

引用次数: 0

摘要

在溶剂热条件下制备了具有16-MR通道的超高质子导电性的磷酸镁草酸盐，分子式为[Mg2(H2O)(HPO3)(C2O4)2](C6N2H16)0.5·（C2NH8）·H2O(1)。在75°C和98% RH（相对湿度）下，最佳质子电导率高达1.15 × 10-2 S cm-1，超过了所有金属磷酸盐/磷酸盐-草酸盐材料的电导率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A magnesium phosphite-oxalate with 16-MR channels showing ultrahigh proton conductivity†

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A magnesium phosphite-oxalate with 16-MR channels showing ultrahigh proton conductivity†

An ultrahigh proton-conductive magnesium phosphite-oxalate showing 16-MR channels, formulated as [Mg₂(H₂O)(HPO₃)(C₂O₄)₂](C₆N₂H₁₆)_0.5·(C₂NH₈)·H₂O (1), was prepared under solvothermal conditions. The optimum proton conductivity is up to 1.15 × 10⁻² S cm⁻¹ at 75 °C and 98% RH (relative humidity), which exceeds the conductivity of all metal phosphate/phosphite-oxalate materials.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.