{"title":"结合非金属氧化物材料在可见光下分解水的Z-Scheme光催化剂体系的开发：（CuGa）0.5ZnS2作为h2 -析出光催化剂和TaON作为o2 -析出光催化剂","authors":"Misa Moriya, Shunya Yoshino, Makoto Kobayashi, Hideki Kato, Yun Hau Ng, Akihide Iwase","doi":"10.1002/aesr.202400371","DOIUrl":null,"url":null,"abstract":"<p>Water splitting under visible light irradiation using a Z-scheme system combining nonmetal oxides of TaON and (CuGa)<sub>0.5</sub>ZnS<sub>2</sub> is demonstrated. The key factors lie in coloading with Ir and CoO<sub><i>x</i></sub> cocatalysts on TaON and using reduced graphene oxide (RGO) as a solid-state electron mediator. Ir is loaded by an impregnation method, while CoO<sub><i>x</i></sub> is loaded by either impregnation or photodeposition methods. Loaded Ir boosts the electron migration from TaON to RGO, and loaded CoO<sub><i>x</i></sub> works as an active site for O<sub>2</sub> evolution. Photocatalytic reduction of graphene oxide to RGO accompanied by simultaneous oxidation of Co<sup>2+</sup> ions to CoO<sub><i>x</i></sub> over Ir-loaded TaON is the optimum process for the formation of an RGO-(CoO<sub><i>x</i></sub>/Ir/TaON) composite.</p>","PeriodicalId":29794,"journal":{"name":"Advanced Energy and Sustainability Research","volume":"6 7","pages":""},"PeriodicalIF":5.7000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400371","citationCount":"0","resultStr":"{\"title\":\"Development of Z-Scheme Photocatalyst Systems Combining Nonmetal Oxide Materials for Water Splitting under Visible Light Irradiation: (CuGa)0.5ZnS2 as a H2-Evolving Photocatalyst and TaON as an O2-Evolving Photocatalyst\",\"authors\":\"Misa Moriya, Shunya Yoshino, Makoto Kobayashi, Hideki Kato, Yun Hau Ng, Akihide Iwase\",\"doi\":\"10.1002/aesr.202400371\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Water splitting under visible light irradiation using a Z-scheme system combining nonmetal oxides of TaON and (CuGa)<sub>0.5</sub>ZnS<sub>2</sub> is demonstrated. The key factors lie in coloading with Ir and CoO<sub><i>x</i></sub> cocatalysts on TaON and using reduced graphene oxide (RGO) as a solid-state electron mediator. Ir is loaded by an impregnation method, while CoO<sub><i>x</i></sub> is loaded by either impregnation or photodeposition methods. Loaded Ir boosts the electron migration from TaON to RGO, and loaded CoO<sub><i>x</i></sub> works as an active site for O<sub>2</sub> evolution. Photocatalytic reduction of graphene oxide to RGO accompanied by simultaneous oxidation of Co<sup>2+</sup> ions to CoO<sub><i>x</i></sub> over Ir-loaded TaON is the optimum process for the formation of an RGO-(CoO<sub><i>x</i></sub>/Ir/TaON) composite.</p>\",\"PeriodicalId\":29794,\"journal\":{\"name\":\"Advanced Energy and Sustainability Research\",\"volume\":\"6 7\",\"pages\":\"\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-01-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aesr.202400371\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Energy and Sustainability Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://advanced.onlinelibrary.wiley.com/doi/10.1002/aesr.202400371\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Energy and Sustainability Research","FirstCategoryId":"1085","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/aesr.202400371","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Development of Z-Scheme Photocatalyst Systems Combining Nonmetal Oxide Materials for Water Splitting under Visible Light Irradiation: (CuGa)0.5ZnS2 as a H2-Evolving Photocatalyst and TaON as an O2-Evolving Photocatalyst
Water splitting under visible light irradiation using a Z-scheme system combining nonmetal oxides of TaON and (CuGa)0.5ZnS2 is demonstrated. The key factors lie in coloading with Ir and CoOx cocatalysts on TaON and using reduced graphene oxide (RGO) as a solid-state electron mediator. Ir is loaded by an impregnation method, while CoOx is loaded by either impregnation or photodeposition methods. Loaded Ir boosts the electron migration from TaON to RGO, and loaded CoOx works as an active site for O2 evolution. Photocatalytic reduction of graphene oxide to RGO accompanied by simultaneous oxidation of Co2+ ions to CoOx over Ir-loaded TaON is the optimum process for the formation of an RGO-(CoOx/Ir/TaON) composite.
期刊介绍：
Advanced Energy and Sustainability Research is an open access academic journal that focuses on publishing high-quality peer-reviewed research articles in the areas of energy harvesting, conversion, storage, distribution, applications, ecology, climate change, water and environmental sciences, and related societal impacts. The journal provides readers with free access to influential scientific research that has undergone rigorous peer review, a common feature of all journals in the Advanced series. In addition to original research articles, the journal publishes opinion, editorial and review articles designed to meet the needs of a broad readership interested in energy and sustainability science and related fields.
In addition, Advanced Energy and Sustainability Research is indexed in several abstracting and indexing services, including：
CAS: Chemical Abstracts Service (ACS)
Directory of Open Access Journals (DOAJ)
Emerging Sources Citation Index (Clarivate Analytics)
INSPEC (IET)
Web of Science (Clarivate Analytics).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
