无膜结构氧化还原液流电池

IF 16.3 1区 工程技术 Q1 ENERGY & FUELS
Feilin Yu , Puiki Leung , Lei Wei , Akeel Shah , Frank C. Walsh , Tianshou Zhao , Qiang Liao
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引用次数: 0

摘要

这篇全面的综述批判性地探讨了氧化还原液流电池(rfb)无膜架构发展的最新进展和创新策略,这是解决对安全、可扩展和具有成本效益的能源存储解决方案日益增长的需求的有前途的途径。随着可再生能源的日益整合和电网对高效电力调节的需求日益增长,可再生燃料电池的适应性和固有的安全性使其成为传统电池的强大替代品。对无膜设计的探索突出了克服膜基系统的复杂性和成本的战略举措。特定方面包括利用层流消除对膜的需求的微流体细胞,解决与规模和功率输出相关的挑战。双相电池利用不混相电解质,通过选择合适的活性材料和溶剂,提供了提高效率和减轻交叉污染的新方法。此外,本文还研究了电沉积阳极的混合液流电池,揭示了抵消枝晶生长和电短路的方法,从而提高了电解质成分和延长了电极的耐用性。溴氢rfb还讨论了其利用气液相相互作用的独特能力,重点介绍了在高电流密度下改善操作和增强质量输运的方法。该分析指出了无膜架构面临的主要挑战,如效率提高、可扩展性和交叉缓解,同时提出了液流电池设计、电极材料和电解质工程方面的创新,以推动该技术走向实际的大规模应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Membraneless-architectured redox flow batteries
This comprehensive review critically explores the latest advancements and innovative strategies in the development of membraneless architectures for redox flow batteries (RFBs), a promising avenue for addressing the burgeoning demands for safe, scalable and cost-effective energy storage solutions. With the increasing integration of renewable energy sources and the growing need for efficient power regulation in grids, the adaptability and inherent safety of RFBs position them as a formidable alternative to conventional batteries. The exploration into membraneless designs highlights a strategic move towards overcoming the complexity and costs associated with membrane-based systems. Particular aspects include microfluidic cells that leverage laminar flow to eliminate the need for membranes, addressing challenges associated with scale and power output. Biphasic batteries, utilizing immiscible electrolytes, offer novel approaches to enhance efficiency and mitigate cross-contamination, through the selection of suitable active materials and solvents. Furthermore, the review examines hybrid flow batteries with electrodeposited anodes, uncovering methods to counteract dendritic growth and electrical short-circuits, thus enhancing electrolyte compositions and extending electrode durability. Hydrogen-bromine RFBs are also discussed for their unique ability to utilize gas and liquid phase interactions, highlighting methods to improve operation at high current densities and enhance mass transport. The analysis identifies key challenges across membraneless architectures, such as efficiency enhancement, scalability and crossover mitigation, while proposing innovations in flow cell design, electrode materials and electrolyte engineering to advance the technology towards practical, large-scale applications.
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来源期刊
Renewable and Sustainable Energy Reviews
Renewable and Sustainable Energy Reviews 工程技术-能源与燃料
CiteScore
31.20
自引率
5.70%
发文量
1055
审稿时长
62 days
期刊介绍: The mission of Renewable and Sustainable Energy Reviews is to disseminate the most compelling and pertinent critical insights in renewable and sustainable energy, fostering collaboration among the research community, private sector, and policy and decision makers. The journal aims to exchange challenges, solutions, innovative concepts, and technologies, contributing to sustainable development, the transition to a low-carbon future, and the attainment of emissions targets outlined by the United Nations Framework Convention on Climate Change. Renewable and Sustainable Energy Reviews publishes a diverse range of content, including review papers, original research, case studies, and analyses of new technologies, all featuring a substantial review component such as critique, comparison, or analysis. Introducing a distinctive paper type, Expert Insights, the journal presents commissioned mini-reviews authored by field leaders, addressing topics of significant interest. Case studies undergo consideration only if they showcase the work's applicability to other regions or contribute valuable insights to the broader field of renewable and sustainable energy. Notably, a bibliographic or literature review lacking critical analysis is deemed unsuitable for publication.
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