n -磺酰基酮胺和炔的协同光氧化还原/钴催化不对称[3 + 2]环化

IF 9.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

CCS Chemistry Pub Date : 2025-07-05 DOI:10.31635/ccschem.025.202505699

Wei Xiong, Rui-Rui Zhao, Hui-Shuang Wang, Liang-Qiu Lu, Ke Gao & Wen-Jing Xiao1Hubei Engineering Research Center for Photochemistry and Technology, Engineering Research Centre of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079 Hubei2Wuhan Institute of Photochemistry and Technology, Wuhan, 430082 Hubei3State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 200032 Shanghai

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引用次数: 0

摘要

CCS化学，领先于印刷。苯唑磺胺类药物具有抗菌、抗糖尿病和抗癌活性，但合成手性螺环磺胺类药物仍然具有挑战性。为了克服这个问题，我们开发了一种光诱导的n -磺酰基不对称[3+2]环化方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Asymmetric [3 + 2] Annulation of N-Sulfonyl Ketimines and Alkynes via Synergistic Photoredox/Cobalt Catalysis

CCS Chemistry, Ahead of Print.
Benzosultams exhibit antibacterial, antidiabetic, and anticancer activities, yet synthesizing chiral spirocyclic sultams remains challenging. To overcome this issue, we developed a photoinduced cocatalyzed asymmetric [3+2] annulation ofN-sulfonyl ...

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来源期刊

CCS Chemistry Chemistry-General Chemistry

CiteScore

13.60

自引率

13.40%

发文量

475

审稿时长

10 weeks

期刊介绍： CCS Chemistry, the flagship publication of the Chinese Chemical Society, stands as a leading international chemistry journal based in China. With a commitment to global outreach in both contributions and readership, the journal operates on a fully Open Access model, eliminating subscription fees for contributing authors. Issued monthly, all articles are published online promptly upon reaching final publishable form. Additionally, authors have the option to expedite the posting process through Immediate Online Accepted Article posting, making a PDF of their accepted article available online upon journal acceptance.