烟尘氧化用钴基氧化物催化剂的研究进展:通过改性和形态控制提高催化性能。

Smart molecules : open access Pub Date : 2024-10-29 eCollection Date: 2024-12-01 DOI:10.1002/smo.20240024
Tingyi Zhao, Zuguo Song, Chengchun Wu, Yuanjun Li, Haoze Li, Yuechang Wei, Siyu Yao, Menglan Xiao, Mingqin Zhao, Bing Cui
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引用次数: 0

摘要

柴油发动机的广泛使用导致了严重的环境污染,由于排放的污染物,特别是烟尘颗粒。这些污染物对公众健康有害。目前,去除油烟颗粒最有效的方法之一是催化柴油颗粒过滤器后处理技术,该技术要求催化剂具有优异的低温活性。与应用广泛的氧化铈相比,氧化钴因其氧化还原能力强、形态易于控制等优点,近年来在过渡金属氧化物中得到了广泛的研究。本文阐述了掺杂、负载、固溶体等改性技术对钴基催化剂烟尘氧化催化性能的影响。在此基础上,进一步综述了具有特定尺寸结构和形态的钴基氧化物催化剂在烟尘氧化中的研究进展。最后,对钴基催化剂在烟尘氧化中的理论基础和应用研究面临的挑战进行了展望。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Advancements in cobalt-based oxide catalysts for soot oxidation: Enhancing catalytic performance through modification and morphology control.

The widespread use of diesel engines results in significant environmental contamination due to emitted pollutants, particularly soot particles. These pollutants are detrimental to public health. At present, one of the most effective ways to remove soot particles is the catalytic diesel particulate filter after-treatment technology, which requires the catalyst to have superior low temperature activity. Compared with cerium oxide which is widely used, cobalt oxide in transition metal oxides has been widely studied in recent years because of its high redox ability and easy to control morphology. This paper elaborates on the influence of modification techniques such as doping, loading, and solid solution on the catalytic performance of cobalt-based catalysts in soot oxidation. Along the same lines, it further reviews the research progress on cobalt-based oxide catalysts with specific dimensional structures and morphologies in soot oxidation. Finally, it provides an outlook on the challenges faced by the theoretical basis and applied research of cobalt-based catalysts in soot oxidation.

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