γ和α / γ辐照下BeO TL信号半衰期的计算

IF 3 4区 化学 Q2 CHEMISTRY, ANALYTICAL
Luminescence Pub Date : 2025-07-09 DOI:10.1002/bio.70251
Rodrigo Martinez-Baltezar, Carlos M. Martínez-Martínez, L. Alberto Medina-Juárez, Gustavo Sánchez-Santacruz, Juan Azorín-Nieto
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引用次数: 0

摘要

研究了BeO陶瓷(Thermalox 995)在γ和α / γ辐照下的热释光(TL)性能。两种情况下的辉光曲线在348±1 K, 477±2 K和616±1 K处都有三个主峰。γ诱导峰的活化能分别为0.76±0.03 eV、1.18±0.04 eV和1.11±0.02 eV;在α / γ辐照下,这些值略有增加,分别为0.81±0.02 eV、1.22±0.03 eV和1.18±0.01 eV。动力学级数接近一级,在477 K峰观察到的数值略高。根据这些参数,计算了TL组分的半衰期。伽马:131秒,1.92年和522年;对于α / γ: 168s, 5.07年和2067年。五个样本的衰落实验表明,第一个峰值与理论值的偏差小于10%。半衰期也随辐照时间的变化而变化,477 K峰呈下降趋势,而616 K峰呈上升趋势,表明陷阱填充机制存在差异。反褶积分析表明,在两种辐照类型下,第二个峰(约477 K)表现出最线性的剂量响应。这些结果强调了分析半衰期行为对于了解BeO作为剂量学材料在不同辐照条件下的稳定性和性能的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation

Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation

Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation

Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation

Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation

The thermoluminescent (TL) properties of BeO ceramics (Thermalox 995) were investigated under gamma and alpha/gamma irradiation. Glow curves in both cases exhibit three main peaks at 348 ± 1 K, 477 ± 2 K, and 616 ± 1 K. Activation energies for gammainduced peaks are 0.76 ± 0.03 eV, 1.18 ± 0.04 eV, and 1.11 ± 0.02 eV; these increase slightly under alpha/gamma irradiation to 0.81 ± 0.02 eV, 1.22 ± 0.03 eV, and 1.18 ± 0.01 eV. The kinetic orders are close to first order, with slightly higher values observed for the 477 K peak. Based on these parameters, the half-lives of the TL components were calculated. For gamma: 131 s, 1.92 years, and 522 years; and for alpha/gamma: 168 s, 5.07 years, and 2067 years. Fading experiments on five samples showed deviations of less than 10% from theoretical values for the first peak. The half-life also varied with irradiation time: the 477 K peak showed a decreasing trend, while the 616 K peak increased, indicating differences in trap-filling mechanisms. Deconvolution analysis revealed that the second peak (around 477 K) exhibits the most linear dose response under both irradiation types. These results underscore the significance of analyzing half-life behavior to understand the stability and performance of BeO as a dosimetric material under varied irradiation conditions.

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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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