Rodrigo Martinez-Baltezar, Carlos M. Martínez-Martínez, L. Alberto Medina-Juárez, Gustavo Sánchez-Santacruz, Juan Azorín-Nieto
{"title":"γ和α / γ辐照下BeO TL信号半衰期的计算","authors":"Rodrigo Martinez-Baltezar, Carlos M. Martínez-Martínez, L. Alberto Medina-Juárez, Gustavo Sánchez-Santacruz, Juan Azorín-Nieto","doi":"10.1002/bio.70251","DOIUrl":null,"url":null,"abstract":"<p>The thermoluminescent (TL) properties of BeO ceramics (Thermalox 995) were investigated under gamma and alpha/gamma irradiation. Glow curves in both cases exhibit three main peaks at 348 ± 1 K, 477 ± 2 K, and 616 ± 1 K. Activation energies for gammainduced peaks are 0.76 ± 0.03 eV, 1.18 ± 0.04 eV, and 1.11 ± 0.02 eV; these increase slightly under alpha/gamma irradiation to 0.81 ± 0.02 eV, 1.22 ± 0.03 eV, and 1.18 ± 0.01 eV. The kinetic orders are close to first order, with slightly higher values observed for the 477 K peak. Based on these parameters, the half-lives of the TL components were calculated. For gamma: 131 s, 1.92 years, and 522 years; and for alpha/gamma: 168 s, 5.07 years, and 2067 years. Fading experiments on five samples showed deviations of less than 10% from theoretical values for the first peak. The half-life also varied with irradiation time: the 477 K peak showed a decreasing trend, while the 616 K peak increased, indicating differences in trap-filling mechanisms. Deconvolution analysis revealed that the second peak (around 477 K) exhibits the most linear dose response under both irradiation types. These results underscore the significance of analyzing half-life behavior to understand the stability and performance of BeO as a dosimetric material under varied irradiation conditions.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"40 7","pages":""},"PeriodicalIF":3.0000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.70251","citationCount":"0","resultStr":"{\"title\":\"Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation\",\"authors\":\"Rodrigo Martinez-Baltezar, Carlos M. Martínez-Martínez, L. Alberto Medina-Juárez, Gustavo Sánchez-Santacruz, Juan Azorín-Nieto\",\"doi\":\"10.1002/bio.70251\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The thermoluminescent (TL) properties of BeO ceramics (Thermalox 995) were investigated under gamma and alpha/gamma irradiation. Glow curves in both cases exhibit three main peaks at 348 ± 1 K, 477 ± 2 K, and 616 ± 1 K. Activation energies for gammainduced peaks are 0.76 ± 0.03 eV, 1.18 ± 0.04 eV, and 1.11 ± 0.02 eV; these increase slightly under alpha/gamma irradiation to 0.81 ± 0.02 eV, 1.22 ± 0.03 eV, and 1.18 ± 0.01 eV. The kinetic orders are close to first order, with slightly higher values observed for the 477 K peak. Based on these parameters, the half-lives of the TL components were calculated. For gamma: 131 s, 1.92 years, and 522 years; and for alpha/gamma: 168 s, 5.07 years, and 2067 years. Fading experiments on five samples showed deviations of less than 10% from theoretical values for the first peak. The half-life also varied with irradiation time: the 477 K peak showed a decreasing trend, while the 616 K peak increased, indicating differences in trap-filling mechanisms. Deconvolution analysis revealed that the second peak (around 477 K) exhibits the most linear dose response under both irradiation types. These results underscore the significance of analyzing half-life behavior to understand the stability and performance of BeO as a dosimetric material under varied irradiation conditions.</p>\",\"PeriodicalId\":49902,\"journal\":{\"name\":\"Luminescence\",\"volume\":\"40 7\",\"pages\":\"\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.70251\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Luminescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/bio.70251\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Luminescence","FirstCategoryId":"92","ListUrlMain":"https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/bio.70251","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Calculation of the Half-Life for the TL Signal of BeO Under Gamma and Alfa/Gamma Irradiation
The thermoluminescent (TL) properties of BeO ceramics (Thermalox 995) were investigated under gamma and alpha/gamma irradiation. Glow curves in both cases exhibit three main peaks at 348 ± 1 K, 477 ± 2 K, and 616 ± 1 K. Activation energies for gammainduced peaks are 0.76 ± 0.03 eV, 1.18 ± 0.04 eV, and 1.11 ± 0.02 eV; these increase slightly under alpha/gamma irradiation to 0.81 ± 0.02 eV, 1.22 ± 0.03 eV, and 1.18 ± 0.01 eV. The kinetic orders are close to first order, with slightly higher values observed for the 477 K peak. Based on these parameters, the half-lives of the TL components were calculated. For gamma: 131 s, 1.92 years, and 522 years; and for alpha/gamma: 168 s, 5.07 years, and 2067 years. Fading experiments on five samples showed deviations of less than 10% from theoretical values for the first peak. The half-life also varied with irradiation time: the 477 K peak showed a decreasing trend, while the 616 K peak increased, indicating differences in trap-filling mechanisms. Deconvolution analysis revealed that the second peak (around 477 K) exhibits the most linear dose response under both irradiation types. These results underscore the significance of analyzing half-life behavior to understand the stability and performance of BeO as a dosimetric material under varied irradiation conditions.
期刊介绍:
Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry.
Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.