{"title":"具有优异电绝缘性能的氟化石墨/聚二甲基硅氧烷复合材料","authors":"Xiquan Xiao, Peiyao Du, Zhixing Wang, Jiqiang Tu, Yongfan Lin, Jiawei Wu, Lihua Zhao, Shenli Jia, Lichuan Jia","doi":"10.1016/j.matlet.2025.139066","DOIUrl":null,"url":null,"abstract":"<div><div>Polydimethylsiloxane (PDMS) is widely used as one key packaging materials in power electronic devices due to its good insulation and easy processability. However, it is still required to enhance the insulation performance of PDMS for its applications in modern high power electronic devices. Herein, fluorinated graphite (f-graphite) was employed as a filler to improve the insulation performance of PDMS. It was found that the resultant f-graphite/PDMS composite with 5 wt% f-graphite content exhibited a high volume resistivity of 9.9 × 10<sup>14</sup> Ω·cm, and an enhanced breakdown strength of 47.3 kV/mm, which was far superior to that of pure PDMS (3.3 × 10<sup>13</sup> Ω·cm and 37.8 kV/mm). These findings provided valuable insights into the development of high insulation PDMS materials for power electronic applications.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"399 ","pages":"Article 139066"},"PeriodicalIF":2.7000,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluorinated graphite/polydimethylsiloxane composites with superior electrical insulation\",\"authors\":\"Xiquan Xiao, Peiyao Du, Zhixing Wang, Jiqiang Tu, Yongfan Lin, Jiawei Wu, Lihua Zhao, Shenli Jia, Lichuan Jia\",\"doi\":\"10.1016/j.matlet.2025.139066\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Polydimethylsiloxane (PDMS) is widely used as one key packaging materials in power electronic devices due to its good insulation and easy processability. However, it is still required to enhance the insulation performance of PDMS for its applications in modern high power electronic devices. Herein, fluorinated graphite (f-graphite) was employed as a filler to improve the insulation performance of PDMS. It was found that the resultant f-graphite/PDMS composite with 5 wt% f-graphite content exhibited a high volume resistivity of 9.9 × 10<sup>14</sup> Ω·cm, and an enhanced breakdown strength of 47.3 kV/mm, which was far superior to that of pure PDMS (3.3 × 10<sup>13</sup> Ω·cm and 37.8 kV/mm). These findings provided valuable insights into the development of high insulation PDMS materials for power electronic applications.</div></div>\",\"PeriodicalId\":384,\"journal\":{\"name\":\"Materials Letters\",\"volume\":\"399 \",\"pages\":\"Article 139066\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2025-07-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167577X2501095X\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X2501095X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Fluorinated graphite/polydimethylsiloxane composites with superior electrical insulation
Polydimethylsiloxane (PDMS) is widely used as one key packaging materials in power electronic devices due to its good insulation and easy processability. However, it is still required to enhance the insulation performance of PDMS for its applications in modern high power electronic devices. Herein, fluorinated graphite (f-graphite) was employed as a filler to improve the insulation performance of PDMS. It was found that the resultant f-graphite/PDMS composite with 5 wt% f-graphite content exhibited a high volume resistivity of 9.9 × 1014 Ω·cm, and an enhanced breakdown strength of 47.3 kV/mm, which was far superior to that of pure PDMS (3.3 × 1013 Ω·cm and 37.8 kV/mm). These findings provided valuable insights into the development of high insulation PDMS materials for power electronic applications.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive