原位x射线吸收光谱在析氢反应：见解和应用

IF 31.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Science and Engineering: R: Reports Pub Date : 2025-07-09 DOI:10.1016/j.mser.2025.101061

Zhenglong Li , Xingyu Ding , Da Liu , Jin Zhou , Yong Gao , Yanxia Liu , Lin Jiang , Renbing Wu , Hongge Pan

{"title":"原位x射线吸收光谱在析氢反应：见解和应用","authors":"Zhenglong Li , Xingyu Ding , Da Liu , Jin Zhou , Yong Gao , Yanxia Liu , Lin Jiang , Renbing Wu , Hongge Pan","doi":"10.1016/j.mser.2025.101061","DOIUrl":null,"url":null,"abstract":"<div><div>Hydrogen evolution reaction (HER) as a footstone of hydrogen economy offers a sustainable approach to achieve energy conversion and storage efficiency from intermittent power like solar and wind. Understanding the genuine active sites and the correlation between dynamic structure and activity in HER electrocatalysts is crucial for their rational design and performance optimization. In-situ X-ray absorption spectroscopy (XAS) has emerged as an effective technique to reveal the behavior of the electrocatalyst in real-time. This review offers an extensive overview of the application of in-situ XAS in studying HER electrocatalysts, highlighting its capacity to investigate the electronic and geometric structures of electrocatalysts during HER operation. It begins with fundamentals of HER mechanism and XAS principles, with an emphasis on the experimental setup of in-situ XAS. Thereafter, identifying active sites and investigating structural dynamics for various electrocatalysts during HER process are emphasized. Finally, this review summarizes the challenges and directions for the advancement of in-situ XAS techniques for HER catalysis.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"166 ","pages":"Article 101061"},"PeriodicalIF":31.6000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In-situ X-ray absorption spectroscopy in hydrogen evolution reaction: Insights and applications\",\"authors\":\"Zhenglong Li , Xingyu Ding , Da Liu , Jin Zhou , Yong Gao , Yanxia Liu , Lin Jiang , Renbing Wu , Hongge Pan\",\"doi\":\"10.1016/j.mser.2025.101061\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Hydrogen evolution reaction (HER) as a footstone of hydrogen economy offers a sustainable approach to achieve energy conversion and storage efficiency from intermittent power like solar and wind. Understanding the genuine active sites and the correlation between dynamic structure and activity in HER electrocatalysts is crucial for their rational design and performance optimization. In-situ X-ray absorption spectroscopy (XAS) has emerged as an effective technique to reveal the behavior of the electrocatalyst in real-time. This review offers an extensive overview of the application of in-situ XAS in studying HER electrocatalysts, highlighting its capacity to investigate the electronic and geometric structures of electrocatalysts during HER operation. It begins with fundamentals of HER mechanism and XAS principles, with an emphasis on the experimental setup of in-situ XAS. Thereafter, identifying active sites and investigating structural dynamics for various electrocatalysts during HER process are emphasized. Finally, this review summarizes the challenges and directions for the advancement of in-situ XAS techniques for HER catalysis.</div></div>\",\"PeriodicalId\":386,\"journal\":{\"name\":\"Materials Science and Engineering: R: Reports\",\"volume\":\"166 \",\"pages\":\"Article 101061\"},\"PeriodicalIF\":31.6000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science and Engineering: R: Reports\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927796X2500138X\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Engineering: R: Reports","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927796X2500138X","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

析氢反应（HER）作为氢经济的基石，为实现太阳能和风能等间歇性能源的能量转换和储存效率提供了一种可持续的方法。了解HER电催化剂的真正活性位点以及动态结构与活性之间的关系对其合理设计和性能优化至关重要。原位x射线吸收光谱（XAS）是一种实时揭示电催化剂行为的有效技术。本文综述了原位XAS在HER电催化剂研究中的应用，重点介绍了原位XAS在HER操作过程中研究电催化剂的电子和几何结构的能力。它从she机制和XAS原理的基本原理开始，重点是原位XAS的实验设置。在此基础上，着重研究了各种电催化剂在HER过程中的活性位点和结构动力学。最后，综述了原位XAS技术在HER催化中的应用面临的挑战和发展方向。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

In-situ X-ray absorption spectroscopy in hydrogen evolution reaction: Insights and applications

Hydrogen evolution reaction (HER) as a footstone of hydrogen economy offers a sustainable approach to achieve energy conversion and storage efficiency from intermittent power like solar and wind. Understanding the genuine active sites and the correlation between dynamic structure and activity in HER electrocatalysts is crucial for their rational design and performance optimization. In-situ X-ray absorption spectroscopy (XAS) has emerged as an effective technique to reveal the behavior of the electrocatalyst in real-time. This review offers an extensive overview of the application of in-situ XAS in studying HER electrocatalysts, highlighting its capacity to investigate the electronic and geometric structures of electrocatalysts during HER operation. It begins with fundamentals of HER mechanism and XAS principles, with an emphasis on the experimental setup of in-situ XAS. Thereafter, identifying active sites and investigating structural dynamics for various electrocatalysts during HER process are emphasized. Finally, this review summarizes the challenges and directions for the advancement of in-situ XAS techniques for HER catalysis.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Materials Science and Engineering: R: Reports 工程技术-材料科学：综合

CiteScore

60.50

自引率

0.30%

发文量

审稿时长

34 days

期刊介绍： Materials Science & Engineering R: Reports is a journal that covers a wide range of topics in the field of materials science and engineering. It publishes both experimental and theoretical research papers, providing background information and critical assessments on various topics. The journal aims to publish high-quality and novel research papers and reviews. The subject areas covered by the journal include Materials Science (General), Electronic Materials, Optical Materials, and Magnetic Materials. In addition to regular issues, the journal also publishes special issues on key themes in the field of materials science, including Energy Materials, Materials for Health, Materials Discovery, Innovation for High Value Manufacturing, and Sustainable Materials development.