基于金属有机框架的坚固和先进材料，用于从水中吸收和光催化减缓非甾体抗炎药

IF 7.9 3区材料科学 Q1 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY

Materials Today Sustainability Pub Date : 2025-06-23 DOI:10.1016/j.mtsust.2025.101164

Arooj Sarwar , Bakhtawar Sajjad , Muhammad Waqas , Fareeha Shakeel , Hira Jabir , Muhammad Imran Din , Azeem Intisar , Adeel Afzal

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引用次数: 0

摘要

水中非甾体抗炎药（NSAIDs）的存在对环境和健康造成了相当大的威胁，因为它们是最广泛使用的治疗疼痛、炎症和发烧的药物之一。金属有机骨架（mof）及其衍生物在非甾体抗炎药的吸收和光催化减缓方面显示出巨大的潜力。它们的大表面积，可调节的孔结构和催化特性使它们成为水处理的优秀候选者。大量的研究报道了坚固和先进的mof吸附非甾体抗炎药的显著能力。Zr-MOF （729.92 mg/g）、Cu-II MOF （650 mg/g）、UiO-66-(COOCu)2 （624.3 mg/g）、UiO-66-(COOFe)2 （769.1 mg/g）和UiO66-NH2 （555 mg/g）等均表现出显著的吸附能力。另一方面，由于光催化降解是一种将药物成分转化为无毒化合物的低成本、无污染的方法，因此它是去除非甾体抗炎药的另一种重要方法。大多数非甾体抗炎药被最先进的mof衍生Fe2O3/TiO2、solar/MIL-88-A/PS体系、vis/H2O2/HSO3-MIL-53（Fe）、g-C3N4/NH2- mil -125、NH2/MgAl-LDH3和BN/Fe3O4/MIL-53（Fe）复合材料完全降解。本文综述了利用各种mof衍生吸附剂和光催化剂有效去除各种非甾体抗炎药的方法。本文还对各种非甾体抗炎药的发生、作用、毒性和比较进行了综述。然而，也讨论了与MOFs相关的一些主要挑战及其可能的解决方案，以创造可持续的环境。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Metal-organic framework-based robust and advanced materials for the absorptive and photocatalytic mitigation of non-steroidal anti-inflammatory drugs from water

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Metal-organic framework-based robust and advanced materials for the absorptive and photocatalytic mitigation of non-steroidal anti-inflammatory drugs from water

The presence of non-steroidal anti-inflammatory drugs (NSAIDs) in water poses a considerable environmental and health threat since they are among the most widely used remedies for pain, inflammation, and fever. Metal-organic frameworks (MOFs) and their derivatives have shown significant potential for the absorptive and photocatalytic mitigation of NSAIDs. Their large surface area, adjustable pore structure, and catalytic characteristics make them excellent candidates for water treatment. Numerous investigations reported the remarkable ability of robust and advanced MOFs to adsorb NSAIDs. For instance, Zr-MOF (729.92 mg/g), Cu-II MOF (650 mg/g), UiO-66-(COOCu)₂ (624.3 mg/g), UiO-66-(COOFe)₂ (769.1 mg/g) and UiO66-NH₂ (555 mg/g) etc. have demonstrated remarkable adsorption capacities. On the other hand, as photocatalytic degradation is a low-cost and non-polluting method of converting pharmaceutical components into non-toxic compounds, it is another significantly important methodology for removing NSAIDs. Most NSAIDs are completely degraded by state-of-the-art MOF-derived Fe₂O₃/TiO₂, solar/MIL-88-A/PS system, vis/H₂O₂/HSO₃-MIL-53(Fe), g-C₃N₄/NH₂-MIL-125, NH₂/MgAl-LDH₃ and BN/Fe₃O₄/MIL-53(Fe) composites. This review offers a comprehensive method for effectively removing various kinds of NSAIDs using a variety of MOF-derived adsorbents and photocatalysts. A comprehensive understanding of the occurrence, role, toxicity, and comparison of various NSAIDs was also discussed in this review. However, some major MOFs related challenges and their possible solutions have also been discussed for creating a sustainable environment.

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来源期刊

Materials Today Sustainability Multiple-

CiteScore

5.80

自引率

6.40%

发文量

174

审稿时长

32 days

期刊介绍： Materials Today Sustainability is a multi-disciplinary journal covering all aspects of sustainability through materials science. With a rapidly increasing population with growing demands, materials science has emerged as a critical discipline toward protecting of the environment and ensuring the long term survival of future generations.