钙钛矿纳米晶体的溶液烧结实现了高性能光电器件。

IF 6.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Karthika Vijayan, Yu-Xiang Chen, Pradyumna Kumar Chand, Ting-Chun Huang, Ya-Ping Hsieh and Mario Hofmann
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引用次数: 0

摘要

钙钛矿纳米晶体由于其特殊的可调性质和可扩展的合成而成为光电子应用的有前途的成分。然而,将它们集成到器件中面临着诸如缺陷、载流子传输差和配体干扰等挑战。我们提出了一种液中液碰撞过程,在环境条件下实现了溴化铅钙钛矿纳米晶体的机械聚结成大的、独立的薄片。这种方法利用碰撞过程中产生的局部剪切力来实现纳米晶体烧结、配体去除和溶剂交换。微观分析揭示了大表面烧结域的形成,克服了以前的缺陷和环境稳定性问题。与随机钙钛矿组件相比,该工艺显著改善了烧结纳米晶体的性能。我们证明了陷阱密度的显著降低导致化学稳定性,电荷传输和辐射电荷重组的增强。载流子迁移率的增强使光电探测器的制造具有卓越的响应速度和灵敏度,超越传统方法。这些发现突出了液体撞击处理通过可扩展和高效的纳米晶体组装来推进钙钛矿基光电子学的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

High-performance optoelectronics enabled by solution-based sintering of perovskite nanocrystals†

High-performance optoelectronics enabled by solution-based sintering of perovskite nanocrystals†

Perovskite nanocrystals have emerged as promising constituents for optoelectronic applications due to their exceptional and tunable properties and their scalable synthesis. However, their integration into devices faces challenges such as defects, poor carrier transport, and ligand interference. We present a liquid-in-liquid impingement process that achieves the mechanical coalescence of lead–bromide perovskite nanocrystals into large, free-standing flakes under ambient conditions. This approach leverages localized shear forces generated during impingement to achieve nanocrystal sintering, ligand removal, and solvent exchange. Microscopic analysis reveals the formation of large surface-sintered domains that overcome previous issues of defectiveness and environmental stability. This process results in significant improvements of the sintered nanocrystal properties compared to random perovskite assemblies. We demonstrate a significant decrease in trap density leading to enhanced chemical stability, charge transport and radiative charge recombination. Enhancements in carrier mobility enable the fabrication of photodetectors with exceptional response speed and sensitivity, surpassing conventional methods. These findings highlight the potential of liquid impingement processing for advancing perovskite-based optoelectronics through scalable and efficient nanocrystal assembly.

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来源期刊
Nanoscale Horizons
Nanoscale Horizons Materials Science-General Materials Science
CiteScore
16.30
自引率
1.00%
发文量
141
期刊介绍: Nanoscale Horizons stands out as a premier journal for publishing exceptionally high-quality and innovative nanoscience and nanotechnology. The emphasis lies on original research that introduces a new concept or a novel perspective (a conceptual advance), prioritizing this over reporting technological improvements. Nevertheless, outstanding articles showcasing truly groundbreaking developments, including record-breaking performance, may also find a place in the journal. Published work must be of substantial general interest to our broad and diverse readership across the nanoscience and nanotechnology community.
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