Guobo Wu , Chao Yu , Xishuang Gu , Hourui Cheng , Xu Cheng , Chengji Deng , Jun Ding , Zhenglong Liu , Zhoufu Wang , Hongxi Zhu
{"title":"添加Y2O3的无压烧结Al4O4C陶瓷","authors":"Guobo Wu , Chao Yu , Xishuang Gu , Hourui Cheng , Xu Cheng , Chengji Deng , Jun Ding , Zhenglong Liu , Zhoufu Wang , Hongxi Zhu","doi":"10.1016/j.matchar.2025.115329","DOIUrl":null,"url":null,"abstract":"<div><div>Al<sub>4</sub>O<sub>4</sub>C ceramics were prepared via pressureless sintering, and the effects of Y<sub>2</sub>O<sub>3</sub> content on their densification and mechanical properties were studied. When sintered at 1800 °C for 3 h, Al<sub>4</sub>O<sub>4</sub>C was identified as the major phase, while Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub> formed as a secondary phase. The in situ YAG effectively enhanced the densification of the ceramics and contributed to the improvement in their mechanical properties. The results indicate that the optimization of Y<sub>2</sub>O<sub>3</sub> content plays a crucial role in achieving favorable mechanical performance. Specifically, the flexural strength peaked at 197.3 MPa with 3 wt% Y<sub>2</sub>O<sub>3</sub>, while the highest Vickers hardness and fracture toughness of 14.3 GPa and 2.6 MPa·m<sup>1/2</sup> were obtained with 5 wt% Y<sub>2</sub>O<sub>3</sub>. This study lays a foundation for the future research and application of Al<sub>4</sub>O<sub>4</sub>C ceramics.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"227 ","pages":"Article 115329"},"PeriodicalIF":4.8000,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pressureless sintered Al4O4C ceramics with Y2O3 addition\",\"authors\":\"Guobo Wu , Chao Yu , Xishuang Gu , Hourui Cheng , Xu Cheng , Chengji Deng , Jun Ding , Zhenglong Liu , Zhoufu Wang , Hongxi Zhu\",\"doi\":\"10.1016/j.matchar.2025.115329\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Al<sub>4</sub>O<sub>4</sub>C ceramics were prepared via pressureless sintering, and the effects of Y<sub>2</sub>O<sub>3</sub> content on their densification and mechanical properties were studied. When sintered at 1800 °C for 3 h, Al<sub>4</sub>O<sub>4</sub>C was identified as the major phase, while Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub> formed as a secondary phase. The in situ YAG effectively enhanced the densification of the ceramics and contributed to the improvement in their mechanical properties. The results indicate that the optimization of Y<sub>2</sub>O<sub>3</sub> content plays a crucial role in achieving favorable mechanical performance. Specifically, the flexural strength peaked at 197.3 MPa with 3 wt% Y<sub>2</sub>O<sub>3</sub>, while the highest Vickers hardness and fracture toughness of 14.3 GPa and 2.6 MPa·m<sup>1/2</sup> were obtained with 5 wt% Y<sub>2</sub>O<sub>3</sub>. This study lays a foundation for the future research and application of Al<sub>4</sub>O<sub>4</sub>C ceramics.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"227 \",\"pages\":\"Article 115329\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-06-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325006187\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325006187","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Pressureless sintered Al4O4C ceramics with Y2O3 addition
Al4O4C ceramics were prepared via pressureless sintering, and the effects of Y2O3 content on their densification and mechanical properties were studied. When sintered at 1800 °C for 3 h, Al4O4C was identified as the major phase, while Y3Al5O12 formed as a secondary phase. The in situ YAG effectively enhanced the densification of the ceramics and contributed to the improvement in their mechanical properties. The results indicate that the optimization of Y2O3 content plays a crucial role in achieving favorable mechanical performance. Specifically, the flexural strength peaked at 197.3 MPa with 3 wt% Y2O3, while the highest Vickers hardness and fracture toughness of 14.3 GPa and 2.6 MPa·m1/2 were obtained with 5 wt% Y2O3. This study lays a foundation for the future research and application of Al4O4C ceramics.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.