{"title":"利用工业副产品作为营养物从废弃随机存储器中生物浸出金。","authors":"Ngoc Tu Trinh Tran, Duy Tho Tran, Thi Phuong Thuy Pham, Yeoung-Sang Yun","doi":"10.1016/j.biortech.2025.132938","DOIUrl":null,"url":null,"abstract":"<p><p>Gold (Au) recovery from waste random access memory (WRAM) was successfully achieved through a bioleaching process utilizing Chromobacterium violaceum. In this study, condensed distiller solubles (CDS), a by-product of industrial ethanol fermentation, was used to stimulate cyanide production, thereby enhancing Au dissolution. Prior to bioleaching, selective removal of base metals was conducted using 100 mM Fe<sub>2</sub> (SO<sub>4</sub>)<sub>3</sub>, achieving 99.7 % copper removal without impacting Au content and effectively minimizing competition for cyanide ions. Subsequently, the treated material was used for the Au bioleaching. Bioleaching parameters, including pulp density, CDS concentration, glycine dosage, and pH, were optimized. The highest Au leaching efficiency of 98.6 % was achieved at WRAM pulp density of 10 g/L, CDS concentration of 8 %, glycine concentration of 3 g/L, and pH of 7.0. This integrated strategy, combining selective chemical pretreatment with CDS-enhanced bioleaching, presents a simple, cost-effective, and environmentally sustainable method for efficient Au recovery from electronic waste.</p>","PeriodicalId":258,"journal":{"name":"Bioresource Technology","volume":" ","pages":"132938"},"PeriodicalIF":9.7000,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Utilization of industrial by-products as nutrients for gold bioleaching from waste random access memory.\",\"authors\":\"Ngoc Tu Trinh Tran, Duy Tho Tran, Thi Phuong Thuy Pham, Yeoung-Sang Yun\",\"doi\":\"10.1016/j.biortech.2025.132938\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Gold (Au) recovery from waste random access memory (WRAM) was successfully achieved through a bioleaching process utilizing Chromobacterium violaceum. In this study, condensed distiller solubles (CDS), a by-product of industrial ethanol fermentation, was used to stimulate cyanide production, thereby enhancing Au dissolution. Prior to bioleaching, selective removal of base metals was conducted using 100 mM Fe<sub>2</sub> (SO<sub>4</sub>)<sub>3</sub>, achieving 99.7 % copper removal without impacting Au content and effectively minimizing competition for cyanide ions. Subsequently, the treated material was used for the Au bioleaching. Bioleaching parameters, including pulp density, CDS concentration, glycine dosage, and pH, were optimized. The highest Au leaching efficiency of 98.6 % was achieved at WRAM pulp density of 10 g/L, CDS concentration of 8 %, glycine concentration of 3 g/L, and pH of 7.0. This integrated strategy, combining selective chemical pretreatment with CDS-enhanced bioleaching, presents a simple, cost-effective, and environmentally sustainable method for efficient Au recovery from electronic waste.</p>\",\"PeriodicalId\":258,\"journal\":{\"name\":\"Bioresource Technology\",\"volume\":\" \",\"pages\":\"132938\"},\"PeriodicalIF\":9.7000,\"publicationDate\":\"2025-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bioresource Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1016/j.biortech.2025.132938\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bioresource Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.biortech.2025.132938","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
利用紫色杆菌成功地从废弃随机存取存储器(WRAM)中回收金(Au)。在这项研究中,浓缩的蒸馏物(CDS),工业乙醇发酵的副产物,被用来刺激氰化物的生产,从而促进金的溶解。在生物浸出之前,使用100 mM Fe2 (SO4)3选择性去除贱金属,在不影响Au含量的情况下实现99.7% %的铜去除率,并有效地减少氰化物离子的竞争。随后,将处理后的材料用于金的生物浸出。对浸出工艺参数(矿浆密度、CDS浓度、甘氨酸用量、pH)进行了优化。在WRAM矿浆密度为10 g/L、CDS浓度为8 %、甘氨酸浓度为3 g/L、pH为7.0的条件下,金浸出率最高,达到98.6 %。该综合策略将选择性化学预处理与cds增强生物浸出相结合,为从电子废物中高效回收金提供了一种简单、经济、环保的可持续方法。
Utilization of industrial by-products as nutrients for gold bioleaching from waste random access memory.
Gold (Au) recovery from waste random access memory (WRAM) was successfully achieved through a bioleaching process utilizing Chromobacterium violaceum. In this study, condensed distiller solubles (CDS), a by-product of industrial ethanol fermentation, was used to stimulate cyanide production, thereby enhancing Au dissolution. Prior to bioleaching, selective removal of base metals was conducted using 100 mM Fe2 (SO4)3, achieving 99.7 % copper removal without impacting Au content and effectively minimizing competition for cyanide ions. Subsequently, the treated material was used for the Au bioleaching. Bioleaching parameters, including pulp density, CDS concentration, glycine dosage, and pH, were optimized. The highest Au leaching efficiency of 98.6 % was achieved at WRAM pulp density of 10 g/L, CDS concentration of 8 %, glycine concentration of 3 g/L, and pH of 7.0. This integrated strategy, combining selective chemical pretreatment with CDS-enhanced bioleaching, presents a simple, cost-effective, and environmentally sustainable method for efficient Au recovery from electronic waste.
期刊介绍:
Bioresource Technology publishes original articles, review articles, case studies, and short communications covering the fundamentals, applications, and management of bioresource technology. The journal seeks to advance and disseminate knowledge across various areas related to biomass, biological waste treatment, bioenergy, biotransformations, bioresource systems analysis, and associated conversion or production technologies.
Topics include:
• Biofuels: liquid and gaseous biofuels production, modeling and economics
• Bioprocesses and bioproducts: biocatalysis and fermentations
• Biomass and feedstocks utilization: bioconversion of agro-industrial residues
• Environmental protection: biological waste treatment
• Thermochemical conversion of biomass: combustion, pyrolysis, gasification, catalysis.