Yichen Sun , Shuyuan Tang , Binzhi Zhao , Ning Jiao
{"title":"环己酮好氧合成邻苯二胺的研究","authors":"Yichen Sun , Shuyuan Tang , Binzhi Zhao , Ning Jiao","doi":"10.1039/d5gc01786f","DOIUrl":null,"url":null,"abstract":"<div><div>A novel iodine and copper co-catalyzed method for the direct conversion of cyclohexanones into substituted <em>o</em>-phenylenediamines has been developed. This transformation is notable for its compatibility with a variety of amines and because it utilizes air as a green oxidant under mild conditions.</div></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"27 27","pages":"Pages 8120-8125"},"PeriodicalIF":9.2000,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Aerobic oxidative synthesis of o-phenylenediamines from cyclohexanones†\",\"authors\":\"Yichen Sun , Shuyuan Tang , Binzhi Zhao , Ning Jiao\",\"doi\":\"10.1039/d5gc01786f\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel iodine and copper co-catalyzed method for the direct conversion of cyclohexanones into substituted <em>o</em>-phenylenediamines has been developed. This transformation is notable for its compatibility with a variety of amines and because it utilizes air as a green oxidant under mild conditions.</div></div>\",\"PeriodicalId\":78,\"journal\":{\"name\":\"Green Chemistry\",\"volume\":\"27 27\",\"pages\":\"Pages 8120-8125\"},\"PeriodicalIF\":9.2000,\"publicationDate\":\"2025-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1463926225005084\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1463926225005084","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Aerobic oxidative synthesis of o-phenylenediamines from cyclohexanones†
A novel iodine and copper co-catalyzed method for the direct conversion of cyclohexanones into substituted o-phenylenediamines has been developed. This transformation is notable for its compatibility with a variety of amines and because it utilizes air as a green oxidant under mild conditions.
期刊介绍:
Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.