Elsayed A Elkhatib, Mohamed L Moharem, Ahmed F Saad, Safa Abdelhamed
{"title":"利用从饮用水工业副产品中提取的新型纳米复合材料有效消除污染废水中的铅。","authors":"Elsayed A Elkhatib, Mohamed L Moharem, Ahmed F Saad, Safa Abdelhamed","doi":"10.1186/s13065-025-01549-4","DOIUrl":null,"url":null,"abstract":"<p><p>Industrial and consumer waste can introduce trace metals into a water supply, resulting in detrimental effects on both human health and natural ecosystems. The primary objective of this research is to produce and characterize a new nanocomposite sorbent (Zeolite- nano-drinking water treatment residuals, Ze-nWTR), followed by assessing its effectiveness in removing Pb(II) from wastewater under varying conditions such as solution pH, presence of competing ions, sorbent quantity, temperature, and contact time using batch experiments. The Langmuir and power function models were utilized to accurately depict the Pb (II) adsorption isotherm and kinetic data. The nanocomposite exhibited a maximum adsorption capacity (q<sub>max</sub>) of 198.7 mgg<sup>-1</sup>, which was determined to be 2.6 and 5.5 times greater than the adsorption capacities of nWTR (75 mgg<sup>-1</sup>) and Zeolite (36 mgg<sup>-1</sup>), respectively. Significant increase in sorbed Pb(II) was noticed above the point of zero charge (pH<sub>zpc</sub>) value of nanocomposite (7.2). Thermodynamic experiments demonstrated that Pb adsorption process onto nanocomposite was endothermic and involuntary. The supposed mechanism of Pb (II) sorption onto nanocomposite was discussed. The final results indicated that nanocomposite (Ze-nWTR) can likely apply for Pb(II) removal from wastewater due to its high affinity towards Pb adsorption, repeatedly used, economically and sustainability.</p>","PeriodicalId":496,"journal":{"name":"BMC Chemistry","volume":"19 1","pages":"188"},"PeriodicalIF":4.3000,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12224485/pdf/","citationCount":"0","resultStr":"{\"title\":\"Effective elimination of lead from polluted wastewater utilizing a novel nanocomposite derived from byproducts of drinking water industry.\",\"authors\":\"Elsayed A Elkhatib, Mohamed L Moharem, Ahmed F Saad, Safa Abdelhamed\",\"doi\":\"10.1186/s13065-025-01549-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Industrial and consumer waste can introduce trace metals into a water supply, resulting in detrimental effects on both human health and natural ecosystems. The primary objective of this research is to produce and characterize a new nanocomposite sorbent (Zeolite- nano-drinking water treatment residuals, Ze-nWTR), followed by assessing its effectiveness in removing Pb(II) from wastewater under varying conditions such as solution pH, presence of competing ions, sorbent quantity, temperature, and contact time using batch experiments. The Langmuir and power function models were utilized to accurately depict the Pb (II) adsorption isotherm and kinetic data. The nanocomposite exhibited a maximum adsorption capacity (q<sub>max</sub>) of 198.7 mgg<sup>-1</sup>, which was determined to be 2.6 and 5.5 times greater than the adsorption capacities of nWTR (75 mgg<sup>-1</sup>) and Zeolite (36 mgg<sup>-1</sup>), respectively. Significant increase in sorbed Pb(II) was noticed above the point of zero charge (pH<sub>zpc</sub>) value of nanocomposite (7.2). Thermodynamic experiments demonstrated that Pb adsorption process onto nanocomposite was endothermic and involuntary. The supposed mechanism of Pb (II) sorption onto nanocomposite was discussed. The final results indicated that nanocomposite (Ze-nWTR) can likely apply for Pb(II) removal from wastewater due to its high affinity towards Pb adsorption, repeatedly used, economically and sustainability.</p>\",\"PeriodicalId\":496,\"journal\":{\"name\":\"BMC Chemistry\",\"volume\":\"19 1\",\"pages\":\"188\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12224485/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"BMC Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1186/s13065-025-01549-4\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"BMC Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1186/s13065-025-01549-4","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effective elimination of lead from polluted wastewater utilizing a novel nanocomposite derived from byproducts of drinking water industry.
Industrial and consumer waste can introduce trace metals into a water supply, resulting in detrimental effects on both human health and natural ecosystems. The primary objective of this research is to produce and characterize a new nanocomposite sorbent (Zeolite- nano-drinking water treatment residuals, Ze-nWTR), followed by assessing its effectiveness in removing Pb(II) from wastewater under varying conditions such as solution pH, presence of competing ions, sorbent quantity, temperature, and contact time using batch experiments. The Langmuir and power function models were utilized to accurately depict the Pb (II) adsorption isotherm and kinetic data. The nanocomposite exhibited a maximum adsorption capacity (qmax) of 198.7 mgg-1, which was determined to be 2.6 and 5.5 times greater than the adsorption capacities of nWTR (75 mgg-1) and Zeolite (36 mgg-1), respectively. Significant increase in sorbed Pb(II) was noticed above the point of zero charge (pHzpc) value of nanocomposite (7.2). Thermodynamic experiments demonstrated that Pb adsorption process onto nanocomposite was endothermic and involuntary. The supposed mechanism of Pb (II) sorption onto nanocomposite was discussed. The final results indicated that nanocomposite (Ze-nWTR) can likely apply for Pb(II) removal from wastewater due to its high affinity towards Pb adsorption, repeatedly used, economically and sustainability.
期刊介绍:
BMC Chemistry, formerly known as Chemistry Central Journal, is now part of the BMC series journals family.
Chemistry Central Journal has served the chemistry community as a trusted open access resource for more than 10 years – and we are delighted to announce the next step on its journey. In January 2019 the journal has been renamed BMC Chemistry and now strengthens the BMC series footprint in the physical sciences by publishing quality articles and by pushing the boundaries of open chemistry.