利用从饮用水工业副产品中提取的新型纳米复合材料有效消除污染废水中的铅。

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Elsayed A Elkhatib, Mohamed L Moharem, Ahmed F Saad, Safa Abdelhamed
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引用次数: 0

摘要

工业和消费废物可将微量金属引入供水系统,对人类健康和自然生态系统造成有害影响。本研究的主要目的是生产和表征一种新型纳米复合吸附剂(沸石-纳米饮用水处理残留物,泽- nwtr),然后通过批处理实验评估其在不同条件下(如溶液pH、竞争离子的存在、吸附剂量、温度和接触时间)去除废水中铅(II)的有效性。利用Langmuir和幂函数模型准确地描述了Pb (II)吸附等温线和动力学数据。纳米复合材料的最大吸附量(qmax)为198.7 mg -1,分别是nWTR (75 mg -1)和沸石(36 mg -1)的2.6倍和5.5倍。在纳米复合材料的零电荷点(pHzpc)值(7.2)以上,吸附的Pb(II)显著增加。热力学实验表明,铅在纳米复合材料上的吸附过程是吸热的、非自愿的。讨论了铅(II)在纳米复合材料上的吸附机理。研究结果表明,纳米复合材料具有高亲和力、可重复使用、经济性和可持续性等优点,有望用于废水中Pb(II)的去除。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effective elimination of lead from polluted wastewater utilizing a novel nanocomposite derived from byproducts of drinking water industry.

Industrial and consumer waste can introduce trace metals into a water supply, resulting in detrimental effects on both human health and natural ecosystems. The primary objective of this research is to produce and characterize a new nanocomposite sorbent (Zeolite- nano-drinking water treatment residuals, Ze-nWTR), followed by assessing its effectiveness in removing Pb(II) from wastewater under varying conditions such as solution pH, presence of competing ions, sorbent quantity, temperature, and contact time using batch experiments. The Langmuir and power function models were utilized to accurately depict the Pb (II) adsorption isotherm and kinetic data. The nanocomposite exhibited a maximum adsorption capacity (qmax) of 198.7 mgg-1, which was determined to be 2.6 and 5.5 times greater than the adsorption capacities of nWTR (75 mgg-1) and Zeolite (36 mgg-1), respectively. Significant increase in sorbed Pb(II) was noticed above the point of zero charge (pHzpc) value of nanocomposite (7.2). Thermodynamic experiments demonstrated that Pb adsorption process onto nanocomposite was endothermic and involuntary. The supposed mechanism of Pb (II) sorption onto nanocomposite was discussed. The final results indicated that nanocomposite (Ze-nWTR) can likely apply for Pb(II) removal from wastewater due to its high affinity towards Pb adsorption, repeatedly used, economically and sustainability.

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来源期刊
BMC Chemistry
BMC Chemistry Chemistry-General Chemistry
CiteScore
5.30
自引率
2.20%
发文量
92
审稿时长
27 weeks
期刊介绍: BMC Chemistry, formerly known as Chemistry Central Journal, is now part of the BMC series journals family. Chemistry Central Journal has served the chemistry community as a trusted open access resource for more than 10 years – and we are delighted to announce the next step on its journey. In January 2019 the journal has been renamed BMC Chemistry and now strengthens the BMC series footprint in the physical sciences by publishing quality articles and by pushing the boundaries of open chemistry.
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