Muhammad Faisal Amin, Paweł Gnida, Jan Grzegorz Małecki, Sonia Kotowicz, Radosław Motyka, Ewa Schab-Balcerzak
{"title":"辅助供体和乙基π-间隔剂在染料敏化太阳能电池染料中的作用。","authors":"Muhammad Faisal Amin, Paweł Gnida, Jan Grzegorz Małecki, Sonia Kotowicz, Radosław Motyka, Ewa Schab-Balcerzak","doi":"10.1002/chem.202501351","DOIUrl":null,"url":null,"abstract":"<p>A new donor-donor-<i>π</i>-acceptor 2-cyano-3-(7-(2-(4-methoxyphenyl)ethynyl)-10-ethyl-10<i>H</i>-phenothiazin-3-yl)acrylic acid (<b>PEDCA</b>) has been synthesized in good yield and was characterized using nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR) spectroscopies. The obtained phenothiazine (PTZ) derivative was explored in dye-sensitized and tandem dye-sensitized solar cells (TDSCs). For reference purposes, the devices based on commercial organometallic dye N719 and a similar PTZ-based dye but without auxiliary donor and ethynyl <i>π</i>-spacer, that is, 2-cyano-3-(10-ethyl-10<i>H</i>-phenothiazin-3-yl)acrylic acid (<b>PEC</b>) were used. The experimental results had also been supported by theoretical calculations performed by employing density functional theory. It was observed that the presence of an auxiliary donor and an ethynyl <i>π</i>-spacer in PTZ unexpectedly decreased the molar absorption coefficient. However, this modification positively influenced the dye loading on the photoanode, which led to a 37% increase in the power conversion efficiency (PCE) of the dye-sensitized solar cell (DSSC) compared to the device sensitized with <b>PEC</b>. Further modifications to the device architecture allowed to obtain DSSC with efficiency above 7%. Despite the fact that the molar absorption coefficients of the <b>PEC</b> solution were higher compared to the <b>PEDCA</b> solution, the key issue is the number of dye molecules, which determines the photocurrent obtained, as shown in the following studies.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"31 41","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Role of an Auxiliary Donor and Ethynyl π-Spacer in a New Phenothiazine Derivative as a Dye for Dye-Sensitized Solar Cells\",\"authors\":\"Muhammad Faisal Amin, Paweł Gnida, Jan Grzegorz Małecki, Sonia Kotowicz, Radosław Motyka, Ewa Schab-Balcerzak\",\"doi\":\"10.1002/chem.202501351\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A new donor-donor-<i>π</i>-acceptor 2-cyano-3-(7-(2-(4-methoxyphenyl)ethynyl)-10-ethyl-10<i>H</i>-phenothiazin-3-yl)acrylic acid (<b>PEDCA</b>) has been synthesized in good yield and was characterized using nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR) spectroscopies. The obtained phenothiazine (PTZ) derivative was explored in dye-sensitized and tandem dye-sensitized solar cells (TDSCs). For reference purposes, the devices based on commercial organometallic dye N719 and a similar PTZ-based dye but without auxiliary donor and ethynyl <i>π</i>-spacer, that is, 2-cyano-3-(10-ethyl-10<i>H</i>-phenothiazin-3-yl)acrylic acid (<b>PEC</b>) were used. The experimental results had also been supported by theoretical calculations performed by employing density functional theory. It was observed that the presence of an auxiliary donor and an ethynyl <i>π</i>-spacer in PTZ unexpectedly decreased the molar absorption coefficient. However, this modification positively influenced the dye loading on the photoanode, which led to a 37% increase in the power conversion efficiency (PCE) of the dye-sensitized solar cell (DSSC) compared to the device sensitized with <b>PEC</b>. Further modifications to the device architecture allowed to obtain DSSC with efficiency above 7%. Despite the fact that the molar absorption coefficients of the <b>PEC</b> solution were higher compared to the <b>PEDCA</b> solution, the key issue is the number of dye molecules, which determines the photocurrent obtained, as shown in the following studies.</p>\",\"PeriodicalId\":144,\"journal\":{\"name\":\"Chemistry - A European Journal\",\"volume\":\"31 41\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - A European Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/chem.202501351\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - A European Journal","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/chem.202501351","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Role of an Auxiliary Donor and Ethynyl π-Spacer in a New Phenothiazine Derivative as a Dye for Dye-Sensitized Solar Cells
A new donor-donor-π-acceptor 2-cyano-3-(7-(2-(4-methoxyphenyl)ethynyl)-10-ethyl-10H-phenothiazin-3-yl)acrylic acid (PEDCA) has been synthesized in good yield and was characterized using nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR) spectroscopies. The obtained phenothiazine (PTZ) derivative was explored in dye-sensitized and tandem dye-sensitized solar cells (TDSCs). For reference purposes, the devices based on commercial organometallic dye N719 and a similar PTZ-based dye but without auxiliary donor and ethynyl π-spacer, that is, 2-cyano-3-(10-ethyl-10H-phenothiazin-3-yl)acrylic acid (PEC) were used. The experimental results had also been supported by theoretical calculations performed by employing density functional theory. It was observed that the presence of an auxiliary donor and an ethynyl π-spacer in PTZ unexpectedly decreased the molar absorption coefficient. However, this modification positively influenced the dye loading on the photoanode, which led to a 37% increase in the power conversion efficiency (PCE) of the dye-sensitized solar cell (DSSC) compared to the device sensitized with PEC. Further modifications to the device architecture allowed to obtain DSSC with efficiency above 7%. Despite the fact that the molar absorption coefficients of the PEC solution were higher compared to the PEDCA solution, the key issue is the number of dye molecules, which determines the photocurrent obtained, as shown in the following studies.
期刊介绍:
Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields.
Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world.
All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times.
The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems.
Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.