无过渡金属的k2s2o8促进氧化C-C三键的裂解和酯化反应，生成α-酮酯。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-06-26 DOI:10.1039/D5OB00892A

Jin-Xin Lan, Yu Shu, Yang Zhou, Liu-Yu Shen, Fei Meng and Wen-Chao Yang

引用次数: 0

摘要

报道了一种通过k2s2o8促进氧化C-C三键裂解和酯化反应将炔转化为α-酮酯的可持续方法。这种方法避免了过渡金属催化、光催化剂和纯氧条件，使其既高效又方便。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Transition-metal-free K2S2O8-promoted oxidative C–C triple bond cleavage and esterification leading to α-ketoesters†

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Transition-metal-free K2S2O8-promoted oxidative C–C triple bond cleavage and esterification leading to α-ketoesters†

A sustainable method for converting alkynes into α-ketoesters is reported through K₂S₂O₈-promoted oxidative C–C triple bond cleavage and esterification. This approach avoids transition metal catalysis, photocatalysts, and pure oxygen conditions, making it both efficient and more convenient.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.