{"title":"传热流体:基于氨基酸阴离子液体的离子流体,具有显著的导热性和低粘度†","authors":"Anshu Chandra, Yamini Sudha Sistla, Mir Atiq Ahmed, Durga Vijay Shankar Vasireddy, Nancy Jaglan, Nipu Kumar Das, Tamal Banerjee and Venkata Subbarayudu Sistla","doi":"10.1039/D5RA03752B","DOIUrl":null,"url":null,"abstract":"<p >Present study aims to develop ionic liquid based nanofluids (IoNanofluids) exhibiting low viscosity, high thermal conductivity, thermal stability, high specific heat capacity and colloidal stability for potential heat transfer fluids applications. Four amino acid anion ionic liquids (AAIL) such as 1-butyl,3-metylimidazolium glycinate, 1-butyl,3-metylimidazolium arginate, 1-ethyl,3-metylimidazolium glycinate, 1-ethyl,3-metylimidazolium arginate were synthesized. The IoNanofluids (INF) were developed by adding 0.05 wt% of MWCNT to the AAILs. The effect of MWCNT concentration and surfactant was investigated by developing INFs consisting of 1-butyl, 3-methylimidazolium tetrafluoroborate ([bmim]<small><sup>+</sup></small>[BF<small><sub>4</sub></small>]<small><sup>−</sup></small>) and MWCNT in the range of 0.025–0.1 wt%. The AAILs showed significantly less viscosity (18–8 mPa s at 298 K), higher thermal conductivity and specific heat capacity compared to several conventional ionic liquids. The four AAIL INFs showed 21–40% enhancement in thermal conductivity; very less viscosity (20 mPa s <em>vs.</em> 110 mPa s at 300 K), and remarkably higher specific heat capacity (10 J g<small><sup>−1</sup></small> °C <em>vs.</em> 1 J g<small><sup>−1</sup></small> °C) compared to [bmim]<small><sup>+</sup></small>[BF<small><sub>4</sub></small>]<small><sup>−</sup></small> INF. The AAIL INFs showed fine and homogeneous dispersion of MWCNT and substantially higher colloidal stability (30 days) compared to [bmim]<small><sup>+</sup></small>[BF<small><sub>4</sub></small>]<small><sup>−</sup></small> (7 days) and [bmim]<small><sup>+</sup></small>[BF<small><sub>4</sub></small>]<small><sup>−</sup></small> + MWCNT + CTAB (14 days). The AAIL INFs of present study showed enhanced heat transfer properties than several literature reported INFs made from conventional ionic liquids. Therefore, based on the overall properties, the AAIL INFs developed in present study could be suitable for applications such as heat exchangers, thermal energy storage systems, cooling of microprocessor systems broadly in the temperature range of 0–200 °C.</p>","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 29","pages":" 23146-23164"},"PeriodicalIF":4.6000,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ra/d5ra03752b?page=search","citationCount":"0","resultStr":"{\"title\":\"Heat transfer fluids: amino acid anion ionic liquid based IoNanofluids with remarkable thermal conductivity and low viscosity†\",\"authors\":\"Anshu Chandra, Yamini Sudha Sistla, Mir Atiq Ahmed, Durga Vijay Shankar Vasireddy, Nancy Jaglan, Nipu Kumar Das, Tamal Banerjee and Venkata Subbarayudu Sistla\",\"doi\":\"10.1039/D5RA03752B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Present study aims to develop ionic liquid based nanofluids (IoNanofluids) exhibiting low viscosity, high thermal conductivity, thermal stability, high specific heat capacity and colloidal stability for potential heat transfer fluids applications. 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引用次数: 0
摘要
本研究旨在开发具有低粘度、高导热性、热稳定性、高比热容和胶体稳定性的离子液体基纳米流体(ionanofluid)作为潜在的传热流体应用。合成了1-丁基、3-甲咪唑甘氨酸盐、1-丁基、3-甲咪唑精氨酸盐、1-乙基、3-甲咪唑甘氨酸盐、1-乙基、3-甲咪唑精氨酸盐4种氨基酸阴离子液体。在aail中加入0.05 wt%的MWCNT,制备了离子流体(INF)。通过制备由1-丁基,3-甲基咪唑四氟硼酸盐([bmim]+[BF4]−)和MWCNT在0.025-0.1 wt%范围内组成的纳米碳纳米管,研究了纳米碳纳米管浓度和表面活性剂的影响。与几种传统离子液体相比,aail的粘度明显降低(298 K时为18-8 mPa s),导热系数和比热容更高。4种AAIL INFs的导热系数提高21 ~ 40%;与[bmim]+[BF4]−INF相比,AAIL INF具有更低的粘度(20 mPa s vs. 110 mPa s)和更高的比热容量(10 J g−1°C vs. 1 J g−1°C)。与[bmim]+[BF4]−(7天)和[bmim]+[BF4]−+ MWCNT + CTAB(14天)相比,AAIL INF表现出MWCNT精细均匀的分散和更高的胶体稳定性(30天)。与文献报道的传统离子液体制备的气泡膜相比,本研究制备的气泡膜具有更强的传热性能。因此,基于整体性能,本研究开发的AAIL inf可以在0-200°C的温度范围内广泛适用于热交换器,热能储存系统,微处理器系统的冷却等应用。
Heat transfer fluids: amino acid anion ionic liquid based IoNanofluids with remarkable thermal conductivity and low viscosity†
Present study aims to develop ionic liquid based nanofluids (IoNanofluids) exhibiting low viscosity, high thermal conductivity, thermal stability, high specific heat capacity and colloidal stability for potential heat transfer fluids applications. Four amino acid anion ionic liquids (AAIL) such as 1-butyl,3-metylimidazolium glycinate, 1-butyl,3-metylimidazolium arginate, 1-ethyl,3-metylimidazolium glycinate, 1-ethyl,3-metylimidazolium arginate were synthesized. The IoNanofluids (INF) were developed by adding 0.05 wt% of MWCNT to the AAILs. The effect of MWCNT concentration and surfactant was investigated by developing INFs consisting of 1-butyl, 3-methylimidazolium tetrafluoroborate ([bmim]+[BF4]−) and MWCNT in the range of 0.025–0.1 wt%. The AAILs showed significantly less viscosity (18–8 mPa s at 298 K), higher thermal conductivity and specific heat capacity compared to several conventional ionic liquids. The four AAIL INFs showed 21–40% enhancement in thermal conductivity; very less viscosity (20 mPa s vs. 110 mPa s at 300 K), and remarkably higher specific heat capacity (10 J g−1 °C vs. 1 J g−1 °C) compared to [bmim]+[BF4]− INF. The AAIL INFs showed fine and homogeneous dispersion of MWCNT and substantially higher colloidal stability (30 days) compared to [bmim]+[BF4]− (7 days) and [bmim]+[BF4]− + MWCNT + CTAB (14 days). The AAIL INFs of present study showed enhanced heat transfer properties than several literature reported INFs made from conventional ionic liquids. Therefore, based on the overall properties, the AAIL INFs developed in present study could be suitable for applications such as heat exchangers, thermal energy storage systems, cooling of microprocessor systems broadly in the temperature range of 0–200 °C.
期刊介绍:
An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.