Itzcóatl Rafael Garduño-Ibarra, Zhigang Yan, Sayed Ahmed Ebrahim, Elena Baranova, Jesús González-Cobos, Mathieu Prévot, Philippe Vernoux
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Ni-Based Catalysts for 5-Hydroxymethylfurfural Electrooxidation Coupled with Hydrogen Production
This review presents a comprehensive analysis of Ni-based catalysts for the co-electrolysis of H2O and 5-hydroxymethylfurfural (HMF) under alkaline conditions, enabling the co-production of low-carbon hydrogen and 2,5-furandicarboxylic acid (FDCA), a key biobased platform chemical. First, recent advances in elucidating the mechanism of HMF electrooxidation (HMFOR) to FDCA on Ni are examined. Next, an in-depth evaluation of the HMFOR performance of various Ni-based catalysts is provided, highlighting the effects of doping or combining Ni with transition metals such as Fe, Co, Cu, and Mn, as well as multimetallic compositions. Finally, HMFOR activity is compared across recent studies to identify key trends and propose research directions for scaling this technology to an industrial level.
期刊介绍：
ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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