{"title":"偏高岭土聚合物物理力学性能的实验研究:老化和围压的影响","authors":"Wei Xu , Matthieu Briffaut , Nicolas Gay , Jianfu Shao","doi":"10.1016/j.clay.2025.107910","DOIUrl":null,"url":null,"abstract":"<div><div>Geopolymers are more and more investigated as a promising and sustainable green concrete solution for many engineering applications. A thorough characterization of their physical and mechanical properties is crucial for safety and durability analysis of related structures. This paper investigates the physical and mechanical behaviors of metakaolin-based geopolymer at different ages under uniaxial and triaxial compression conditions. The present study first focuses on the setting time, bulk density, porosity, permeability, and pore structure of selected geopolymer specimens. The emphasis is then placed on the characterization of elastic properties, failure strength and patterns of material through uniaxial and triaxial compression tests. The study reveals that with increasing curing age, the bulk density, porosity, pore volume, and permeability decrease, while one obtains an increase of failure strength, Young’s modulus, internal cohesion, and friction angle. Higher confining pressure enhances failure strength and ductility, shifts cracking mode from axial splitting to inclined shearing, and induces irreversible pore structure changes. Permeability and mechanical behavior show nonlinear dependence on confining pressure. These results bring some new insights on the effects of age and confining pressure on the microstructure, mechanical and transport properties of metakaolin-based geopolymers, potentially supporting engineering design and modeling.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"276 ","pages":"Article 107910"},"PeriodicalIF":5.8000,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental investigation on the physical and mechanical properties of metakaolin-based geopolymers: Effects of aging and confining pressure\",\"authors\":\"Wei Xu , Matthieu Briffaut , Nicolas Gay , Jianfu Shao\",\"doi\":\"10.1016/j.clay.2025.107910\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Geopolymers are more and more investigated as a promising and sustainable green concrete solution for many engineering applications. A thorough characterization of their physical and mechanical properties is crucial for safety and durability analysis of related structures. This paper investigates the physical and mechanical behaviors of metakaolin-based geopolymer at different ages under uniaxial and triaxial compression conditions. The present study first focuses on the setting time, bulk density, porosity, permeability, and pore structure of selected geopolymer specimens. The emphasis is then placed on the characterization of elastic properties, failure strength and patterns of material through uniaxial and triaxial compression tests. The study reveals that with increasing curing age, the bulk density, porosity, pore volume, and permeability decrease, while one obtains an increase of failure strength, Young’s modulus, internal cohesion, and friction angle. Higher confining pressure enhances failure strength and ductility, shifts cracking mode from axial splitting to inclined shearing, and induces irreversible pore structure changes. Permeability and mechanical behavior show nonlinear dependence on confining pressure. These results bring some new insights on the effects of age and confining pressure on the microstructure, mechanical and transport properties of metakaolin-based geopolymers, potentially supporting engineering design and modeling.</div></div>\",\"PeriodicalId\":245,\"journal\":{\"name\":\"Applied Clay Science\",\"volume\":\"276 \",\"pages\":\"Article 107910\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Clay Science\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169131725002157\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Clay Science","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169131725002157","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Experimental investigation on the physical and mechanical properties of metakaolin-based geopolymers: Effects of aging and confining pressure
Geopolymers are more and more investigated as a promising and sustainable green concrete solution for many engineering applications. A thorough characterization of their physical and mechanical properties is crucial for safety and durability analysis of related structures. This paper investigates the physical and mechanical behaviors of metakaolin-based geopolymer at different ages under uniaxial and triaxial compression conditions. The present study first focuses on the setting time, bulk density, porosity, permeability, and pore structure of selected geopolymer specimens. The emphasis is then placed on the characterization of elastic properties, failure strength and patterns of material through uniaxial and triaxial compression tests. The study reveals that with increasing curing age, the bulk density, porosity, pore volume, and permeability decrease, while one obtains an increase of failure strength, Young’s modulus, internal cohesion, and friction angle. Higher confining pressure enhances failure strength and ductility, shifts cracking mode from axial splitting to inclined shearing, and induces irreversible pore structure changes. Permeability and mechanical behavior show nonlinear dependence on confining pressure. These results bring some new insights on the effects of age and confining pressure on the microstructure, mechanical and transport properties of metakaolin-based geopolymers, potentially supporting engineering design and modeling.
期刊介绍:
Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as:
• Synthesis and purification
• Structural, crystallographic and mineralogical properties of clays and clay minerals
• Thermal properties of clays and clay minerals
• Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties
• Interaction with water, with polar and apolar molecules
• Colloidal properties and rheology
• Adsorption, Intercalation, Ionic exchange
• Genesis and deposits of clay minerals
• Geology and geochemistry of clays
• Modification of clays and clay minerals properties by thermal and physical treatments
• Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays)
• Modification by biological microorganisms. etc...