光化学基团转移自由基加成法合成烷基硫氰酸酯

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-03 DOI:10.1039/D5CC02140E

Shyamal Pramanik, Injamam Ul Hoque and Soumitra Maity

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引用次数: 0

摘要

本文探索了一组烷基硫氰酸酯作为烯烃基团转移自由基加成（GTRA）试剂，最终在温和条件下实现了烯烃的同源化。因此，利用光诱导的C-S键裂解，作为-SCN和各种烷基插入到烯烃上的手段，创建一个注入硫氰酸盐功能的小分子文库。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Homologation of alkyl thiocyanates through photochemical group transfer radical addition (GTRA)†

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Homologation of alkyl thiocyanates through photochemical group transfer radical addition (GTRA)†

Herein, a set of alkyl thiocyanates was explored as reagents for group transfer radical addition (GTRA) to alkenes, which eventually resulted in their homologation under mild conditions. The photo-induced C–S bond cleavage is hereby taken advantage of, serving as a means of inserting –SCN and diverse alkyl groups onto alkenes to create a library of small molecules infused with thiocyanate functionality.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.