金属原子化学是三价铁Fe， Co， Ni的同感单核和双核异腈化合物的直接途径

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-07-02 DOI:10.1039/D5DT01275A

Johannes M. Emmert, Jörg Rust, Christian W. Lehmann and Jörg J. Schneider

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引用次数: 0

摘要

铁、镍和钴的金属原子蒸气与甲苯共缩合，然后在-30°至-78°C之间与异腈直接反应，得到稳定的同色金属异腈配合物。以Fe、Ni、Co为原料，以DippNC （Dipp = 2,6-(CH(CH3)2)2C6H3）和4-氟苯基异腈（4-FPI）为原料，收率高。与以前报道的合成相比，这种方法提供了一种有效和直接的方法。

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Metal atom chemistry as a direct pathway to access homoleptic mono- and dinuclear isonitrile compounds of the iron triad Fe, Co, and Ni†

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Metal atom chemistry as a direct pathway to access homoleptic mono- and dinuclear isonitrile compounds of the iron triad Fe, Co, and Ni†

The co-condensation of atomic metal vapors of iron, nickel and cobalt with toluene, followed by a direct reaction with isonitriles, between −30 °C and −78 °C, yields stable homoleptic metal isonitrile complexes. Complexes of Fe, Ni, and Co with DippNC (Dipp = 2,6-(CH(CH₃)₂)₂C₆H₃) and 4-fluorophenylisonitrile (4-FPI) are obtained in high yields using this method. This method offers an efficient and straightforward approach compared to previously reported syntheses.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.