{"title":"有机自由基包合mof和自由基mof的研究进展。","authors":"Christophe Adrien Ndamyabera, Henrietta Wakuna Langmi","doi":"10.1002/open.202500069","DOIUrl":null,"url":null,"abstract":"<p><p>Organic radicals are attractive materials due to their structures which contain unpaired electrons susceptible to charge transfer upon excitation. They possess potential properties such as optical properties, magnetism, and electrical conductivity. However, they are usually unstable impeding their further advancement and application. Organic radicals can serve as guest molecules in porous solids specifically metal-organic frameworks (MOFs) thereby gaining stability. MOFs are of interest due to their potential properties including large surface area and high adsorption capacity. Apart from their incorporation to form organic radical inclusion MOF hybrids, organic radicals can act as ligands in MOFs to yield radical MOFs. These hybrids and radical MOFs often exhibit enhanced properties such as improved catalytic, magnetic, optical, and sensing properties which make them promising for industrial applications. Herein, organic radical inclusion in MOFs and radical MOFs are reviewed. A brief background on organic radicals is presented. Different methods of integrating organic radicals (guests) in channels of MOFs (hosts) and the resulting changes in the physicochemical properties are documented. Furthermore, the use of organic radicals as ligands in the synthesis of radical MOFs is discussed as an alternative to organic radical-MOF inclusion compounds, and the ensuing physicochemical properties are highlighted.</p>","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500069"},"PeriodicalIF":2.5000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent Developments in Organic Radical Inclusion in MOFs and Radical MOFs.\",\"authors\":\"Christophe Adrien Ndamyabera, Henrietta Wakuna Langmi\",\"doi\":\"10.1002/open.202500069\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Organic radicals are attractive materials due to their structures which contain unpaired electrons susceptible to charge transfer upon excitation. They possess potential properties such as optical properties, magnetism, and electrical conductivity. However, they are usually unstable impeding their further advancement and application. Organic radicals can serve as guest molecules in porous solids specifically metal-organic frameworks (MOFs) thereby gaining stability. MOFs are of interest due to their potential properties including large surface area and high adsorption capacity. Apart from their incorporation to form organic radical inclusion MOF hybrids, organic radicals can act as ligands in MOFs to yield radical MOFs. These hybrids and radical MOFs often exhibit enhanced properties such as improved catalytic, magnetic, optical, and sensing properties which make them promising for industrial applications. Herein, organic radical inclusion in MOFs and radical MOFs are reviewed. A brief background on organic radicals is presented. Different methods of integrating organic radicals (guests) in channels of MOFs (hosts) and the resulting changes in the physicochemical properties are documented. Furthermore, the use of organic radicals as ligands in the synthesis of radical MOFs is discussed as an alternative to organic radical-MOF inclusion compounds, and the ensuing physicochemical properties are highlighted.</p>\",\"PeriodicalId\":9831,\"journal\":{\"name\":\"ChemistryOpen\",\"volume\":\" \",\"pages\":\"e2500069\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryOpen\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/open.202500069\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryOpen","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/open.202500069","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Recent Developments in Organic Radical Inclusion in MOFs and Radical MOFs.
Organic radicals are attractive materials due to their structures which contain unpaired electrons susceptible to charge transfer upon excitation. They possess potential properties such as optical properties, magnetism, and electrical conductivity. However, they are usually unstable impeding their further advancement and application. Organic radicals can serve as guest molecules in porous solids specifically metal-organic frameworks (MOFs) thereby gaining stability. MOFs are of interest due to their potential properties including large surface area and high adsorption capacity. Apart from their incorporation to form organic radical inclusion MOF hybrids, organic radicals can act as ligands in MOFs to yield radical MOFs. These hybrids and radical MOFs often exhibit enhanced properties such as improved catalytic, magnetic, optical, and sensing properties which make them promising for industrial applications. Herein, organic radical inclusion in MOFs and radical MOFs are reviewed. A brief background on organic radicals is presented. Different methods of integrating organic radicals (guests) in channels of MOFs (hosts) and the resulting changes in the physicochemical properties are documented. Furthermore, the use of organic radicals as ligands in the synthesis of radical MOFs is discussed as an alternative to organic radical-MOF inclusion compounds, and the ensuing physicochemical properties are highlighted.
期刊介绍:
ChemistryOpen is a multidisciplinary, gold-road open-access, international forum for the publication of outstanding Reviews, Full Papers, and Communications from all areas of chemistry and related fields. It is co-owned by 16 continental European Chemical Societies, who have banded together in the alliance called ChemPubSoc Europe for the purpose of publishing high-quality journals in the field of chemistry and its border disciplines. As some of the governments of the countries represented in ChemPubSoc Europe have strongly recommended that the research conducted with their funding is freely accessible for all readers (Open Access), ChemPubSoc Europe was concerned that no journal for which the ethical standards were monitored by a chemical society was available for such papers. ChemistryOpen fills this gap.