应变依赖的极化子调控抑制钙钛矿纳米线中的载流子衰变以增强CO2光还原。

IF 21.1 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES
Heng Shi, Fengyi Zhong, Shiyong Mou, Chenyu Du, Ye He, Ying Zhou, Jianping Sheng, Fan Dong
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引用次数: 0

摘要

金属卤化物钙钛矿纳米晶体作为一种具有独特性能的高效光催化剂,在能源和环境催化等方面的应用引起了人们的广泛关注。然而,金属卤化物钙钛矿纳米晶体的全部潜力尚未开发。在这项研究中,我们通过应变工程方法合成了一系列具有可定制拉伸应变(0%-1%)的CsPbBr3纳米线,以提高光催化CO2还原性能。中等应变(0.47%)的纳米线具有优异的催化性能,电子消耗率超过300 μmol g-1 h-1, CO的选择性为100%,是未应变样品的5倍。超快光谱、原位漫反射红外傅立叶变换光谱和密度泛函理论计算表明,应变调制极化子的形成延迟了载流子衰变过程(最长时间成分从672 ps增加到2.85 ns),应变调整电子结构降低了*COOH形成的热力学能垒,从而提高了应变样品的性能。我们的研究强调了应变调制极化子行为在金属卤化物钙钛矿光催化剂中的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Strain-dependent polaron regulation suppresses carrier decay in perovskite nanowires to enhance CO2 photoreduction.

Metal-halide perovskite nanocrystals, as efficient photocatalysts with unique properties, have attracted significant interest for various applications in energy and environmental catalysis applications. However, the full potential of metal-halide perovskite nanocrystals remains untapped. In this study, we synthesised a series of CsPbBr3 nanowires with tailorable tensile strain (0%-1%) through a strain engineering approach to enhance photocatalytic CO2 reduction performance. Nanowires with moderate strain (0.47%) attained superior catalytic performance with an electron consumption rate exceeding 300 μmol g-1 h-1 and 100% selectivity for CO production, surpassing that of the unstrained sample by five times. Ultrafast spectroscopy, in-situ diffuse reflectance infrared Fourier transform spectroscopy, and density functional theory calculations revealed that the enhanced performance of the strained sample arises from strain-modulated polaron formation, which retards the carrier decay process (with the longest time component increasing from 672 ps to 2.85 ns), as well as strain-tailored electronic structures that lower the thermodynamic energy barrier for *COOH formation. Our study highlights the significance of strain-modulated polaron behaviour in metal-halide perovskite photocatalysts.

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来源期刊
Science Bulletin
Science Bulletin MULTIDISCIPLINARY SCIENCES-
CiteScore
24.60
自引率
2.10%
发文量
8092
期刊介绍: Science Bulletin (Sci. Bull., formerly known as Chinese Science Bulletin) is a multidisciplinary academic journal supervised by the Chinese Academy of Sciences (CAS) and co-sponsored by the CAS and the National Natural Science Foundation of China (NSFC). Sci. Bull. is a semi-monthly international journal publishing high-caliber peer-reviewed research on a broad range of natural sciences and high-tech fields on the basis of its originality, scientific significance and whether it is of general interest. In addition, we are committed to serving the scientific community with immediate, authoritative news and valuable insights into upcoming trends around the globe.
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