{"title":"生物相容性壳聚糖-氧化石墨烯气凝胶的合成、表征及其在反aza- henry型转化中的催化应用","authors":"Hossein Tavakol, Hamidreza Tarkesh","doi":"10.1016/j.jics.2025.101875","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, graphene oxide-chitosan aerogel (GO-CS) with honeycomb structure was prepared using sol-gel and freeze-drying methods. The physicochemical properties of nanocatalyst were investigated by FTIR, TGA, BET, XRD, RAMAN, FESEM-EDS, and elemental mapping to support that cross-linking occurs between the –COOH groups of GO and amine groups of CS and examine the surface properties and porosity of the prepared material. The prepared aerogel material showed appropriate thermal stability, interesting honeycomb-like structure, high porosity, surface functional group versatility, and high surface area, which all of them are the desired properties for catalytic purposes. In continuation, the catalytic activity of the prepared GO-CS has been evaluated in the reaction between β-nitrostyrene derivatives and hydrazine hydrate (N<sub>2</sub>H<sub>4</sub>.H<sub>2</sub>O) in the ethanol as a solvent. Using only 0.3 w% of this aerogel material as a catalyst, the reactions for all 20 derivatives of β-nitrostyrenes were completed in 3 h at 50 °C in almost quantitative yields (98–100 %). The employed catalyst showed high reusability experiments and after six consecutive runs, the reaction remained quantitative.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 8","pages":"Article 101875"},"PeriodicalIF":3.2000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, characterization, and catalytic application of biocompatible chitosan-graphene oxide aerogel in the retro-aza-Henry-type conversion\",\"authors\":\"Hossein Tavakol, Hamidreza Tarkesh\",\"doi\":\"10.1016/j.jics.2025.101875\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, graphene oxide-chitosan aerogel (GO-CS) with honeycomb structure was prepared using sol-gel and freeze-drying methods. The physicochemical properties of nanocatalyst were investigated by FTIR, TGA, BET, XRD, RAMAN, FESEM-EDS, and elemental mapping to support that cross-linking occurs between the –COOH groups of GO and amine groups of CS and examine the surface properties and porosity of the prepared material. The prepared aerogel material showed appropriate thermal stability, interesting honeycomb-like structure, high porosity, surface functional group versatility, and high surface area, which all of them are the desired properties for catalytic purposes. In continuation, the catalytic activity of the prepared GO-CS has been evaluated in the reaction between β-nitrostyrene derivatives and hydrazine hydrate (N<sub>2</sub>H<sub>4</sub>.H<sub>2</sub>O) in the ethanol as a solvent. Using only 0.3 w% of this aerogel material as a catalyst, the reactions for all 20 derivatives of β-nitrostyrenes were completed in 3 h at 50 °C in almost quantitative yields (98–100 %). The employed catalyst showed high reusability experiments and after six consecutive runs, the reaction remained quantitative.</div></div>\",\"PeriodicalId\":17276,\"journal\":{\"name\":\"Journal of the Indian Chemical Society\",\"volume\":\"102 8\",\"pages\":\"Article 101875\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Indian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0019452225003103\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Indian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0019452225003103","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, characterization, and catalytic application of biocompatible chitosan-graphene oxide aerogel in the retro-aza-Henry-type conversion
In this study, graphene oxide-chitosan aerogel (GO-CS) with honeycomb structure was prepared using sol-gel and freeze-drying methods. The physicochemical properties of nanocatalyst were investigated by FTIR, TGA, BET, XRD, RAMAN, FESEM-EDS, and elemental mapping to support that cross-linking occurs between the –COOH groups of GO and amine groups of CS and examine the surface properties and porosity of the prepared material. The prepared aerogel material showed appropriate thermal stability, interesting honeycomb-like structure, high porosity, surface functional group versatility, and high surface area, which all of them are the desired properties for catalytic purposes. In continuation, the catalytic activity of the prepared GO-CS has been evaluated in the reaction between β-nitrostyrene derivatives and hydrazine hydrate (N2H4.H2O) in the ethanol as a solvent. Using only 0.3 w% of this aerogel material as a catalyst, the reactions for all 20 derivatives of β-nitrostyrenes were completed in 3 h at 50 °C in almost quantitative yields (98–100 %). The employed catalyst showed high reusability experiments and after six consecutive runs, the reaction remained quantitative.
期刊介绍:
The Journal of the Indian Chemical Society publishes original, fundamental, theorical, experimental research work of highest quality in all areas of chemistry, biochemistry, medicinal chemistry, electrochemistry, agrochemistry, chemical engineering and technology, food chemistry, environmental chemistry, etc.