{"title":"铀分离用磁性吸附剂:进展、机理和工业应用","authors":"A.S. Suneesh , N. Ramanathan","doi":"10.1016/j.jece.2025.117713","DOIUrl":null,"url":null,"abstract":"<div><div>This review emphasizes on identifying the scope of Magnetic solid-phase adsorbents (MSPS) for the separation of uranium from seawater. MSPS—utilizing the paramagnetic core as part of the uranium-selective adsorbent—enables a faster physical separation of the adsorbent from the aqueous phase, making them an ideal option for facilitating the uranium separation in batch mode without the need of large-scale separation columns. Suitability for batch-mode operation and a higher surface area-to-volume ratio are the other attractions of MSPS. Uranium separation from seawater has been a critical research area since the 1970s, although there has been limited work on the subject. However, with the growing global demand for uranium to meet future energy needs because of demand to reduce carbon emissions by shifting away from fossil fuels. This review highlights an update deliberation on scientific developments across the globe in developing a diverse class of magnetic supported adsorbents for uranium separation, the synthetic procedure, characterization methods, mechanism of interaction, uranium separation efficiency and so on. Due to the limited literature on this topic and the prospective to provide valuable insights into large-scale separation systems based on magnetic solid phase separation, particularly for uranium removal from seawater, the present review identifies significant opportunities for further exploration. This review would stress upon more on the different research development towards materials for magnetic assisted separation of uranium, with current focus towards emphasing materials having industrial scope, theoretical studies towards materials and industrial attempts towards the viability of using magnetic adsorbents.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117713"},"PeriodicalIF":7.2000,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magnetic supported adsorbents for uranium separation: Advances, mechanisms, and industrial applications\",\"authors\":\"A.S. Suneesh , N. Ramanathan\",\"doi\":\"10.1016/j.jece.2025.117713\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This review emphasizes on identifying the scope of Magnetic solid-phase adsorbents (MSPS) for the separation of uranium from seawater. MSPS—utilizing the paramagnetic core as part of the uranium-selective adsorbent—enables a faster physical separation of the adsorbent from the aqueous phase, making them an ideal option for facilitating the uranium separation in batch mode without the need of large-scale separation columns. Suitability for batch-mode operation and a higher surface area-to-volume ratio are the other attractions of MSPS. Uranium separation from seawater has been a critical research area since the 1970s, although there has been limited work on the subject. However, with the growing global demand for uranium to meet future energy needs because of demand to reduce carbon emissions by shifting away from fossil fuels. This review highlights an update deliberation on scientific developments across the globe in developing a diverse class of magnetic supported adsorbents for uranium separation, the synthetic procedure, characterization methods, mechanism of interaction, uranium separation efficiency and so on. Due to the limited literature on this topic and the prospective to provide valuable insights into large-scale separation systems based on magnetic solid phase separation, particularly for uranium removal from seawater, the present review identifies significant opportunities for further exploration. This review would stress upon more on the different research development towards materials for magnetic assisted separation of uranium, with current focus towards emphasing materials having industrial scope, theoretical studies towards materials and industrial attempts towards the viability of using magnetic adsorbents.</div></div>\",\"PeriodicalId\":15759,\"journal\":{\"name\":\"Journal of Environmental Chemical Engineering\",\"volume\":\"13 5\",\"pages\":\"Article 117713\"},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2025-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Environmental Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2213343725024091\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Environmental Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2213343725024091","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Magnetic supported adsorbents for uranium separation: Advances, mechanisms, and industrial applications
This review emphasizes on identifying the scope of Magnetic solid-phase adsorbents (MSPS) for the separation of uranium from seawater. MSPS—utilizing the paramagnetic core as part of the uranium-selective adsorbent—enables a faster physical separation of the adsorbent from the aqueous phase, making them an ideal option for facilitating the uranium separation in batch mode without the need of large-scale separation columns. Suitability for batch-mode operation and a higher surface area-to-volume ratio are the other attractions of MSPS. Uranium separation from seawater has been a critical research area since the 1970s, although there has been limited work on the subject. However, with the growing global demand for uranium to meet future energy needs because of demand to reduce carbon emissions by shifting away from fossil fuels. This review highlights an update deliberation on scientific developments across the globe in developing a diverse class of magnetic supported adsorbents for uranium separation, the synthetic procedure, characterization methods, mechanism of interaction, uranium separation efficiency and so on. Due to the limited literature on this topic and the prospective to provide valuable insights into large-scale separation systems based on magnetic solid phase separation, particularly for uranium removal from seawater, the present review identifies significant opportunities for further exploration. This review would stress upon more on the different research development towards materials for magnetic assisted separation of uranium, with current focus towards emphasing materials having industrial scope, theoretical studies towards materials and industrial attempts towards the viability of using magnetic adsorbents.
期刊介绍:
The Journal of Environmental Chemical Engineering (JECE) serves as a platform for the dissemination of original and innovative research focusing on the advancement of environmentally-friendly, sustainable technologies. JECE emphasizes the transition towards a carbon-neutral circular economy and a self-sufficient bio-based economy. Topics covered include soil, water, wastewater, and air decontamination; pollution monitoring, prevention, and control; advanced analytics, sensors, impact and risk assessment methodologies in environmental chemical engineering; resource recovery (water, nutrients, materials, energy); industrial ecology; valorization of waste streams; waste management (including e-waste); climate-water-energy-food nexus; novel materials for environmental, chemical, and energy applications; sustainability and environmental safety; water digitalization, water data science, and machine learning; process integration and intensification; recent developments in green chemistry for synthesis, catalysis, and energy; and original research on contaminants of emerging concern, persistent chemicals, and priority substances, including microplastics, nanoplastics, nanomaterials, micropollutants, antimicrobial resistance genes, and emerging pathogens (viruses, bacteria, parasites) of environmental significance.