炔的电化学氢三氟甲基化反应

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-01 DOI:10.1039/D5CC02370J

Jihoon Jang and Eun Jin Cho

引用次数: 0

摘要

我们报道了用Langlois试剂作为CF₃源的炔的电化学氢三氟甲基化反应。温和的条件使广泛的官能团耐受和允许后期功能化。机理研究表明，DMSO具有溶剂和氢原子给体的双重作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Electrochemical hydrotrifluoromethylation of alkynes†

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Electrochemical hydrotrifluoromethylation of alkynes†

We report the electrochemical hydrotrifluoromethylation of alkynes using the Langlois reagent as a CF₃ source. The mild conditions enable broad functional group tolerance and allow late-stage functionalization. Mechanistic studies reveal that DMSO serves a dual role as both solvent and hydrogen atom donor.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.