CuFe2O4/PANI纳米复合材料稳健水裂解催化性能的改进

IF 5.6 3区 材料科学 Q1 ELECTROCHEMISTRY
Kiran Razzaq , Abdelaziz Gassoumi , Hala M. Abo-Dief , Mongi Lmami , Abhinav Kumar
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引用次数: 0

摘要

改进可再生的高活性电活性OER(析氧反应)催化剂是满足全球能源需求的重要科学目标。本文研究了用水热法制备CuFe2O4/PANI复合材料。这种复合结构可作为评估基本环境OER有效性的催化剂。样品在1.0 M KOH浓度下表现出优异的OER效率,并通过x射线衍射(XRD)分析证实了其立方相。制备的复合材料具有更大的表面积,提高了OER的催化性能。此外,CuFe2O4/PANI复合材料在1 M KOH条件下对OER具有显著的催化应用,具有优异的稳定性(30 h)和较低的过电位(194 mV),可获得电流密度(j) (10 mA/cm2)。与纯CuFe2O4纳米材料相比,复合材料具有最小的起电位(1.39 V),显著的电化学活性表面积(ECSA)为76.25 cm2,惊人的Tafel图(34 mV/dec)。此外,CuFe2O4的固有电子结构显著提高了OER动力学,强调了其作为贵金属基电催化剂的高效可再生替代品的潜力。这些结果不仅验证了合成的CuFe2O4/PANI纳米复合材料作为一种有前途的OER电催化剂的有效性,而且为其在未来储能系统和大规模可再生能源转换技术中的应用铺平了道路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improvement in catalytic performance of CuFe2O4/PANI nanocomposite for robust water splitting
The improvement of renewable and highly active electroactive catalysts for OER (oxygen evolution reaction) is a crucial scientific objective to meet global energy requirements. This work specifically examines the production of a composite material based on CuFe2O4/PANI using a hydrothermal method. This composite structure serves as a catalyst for assessing effectiveness of OER in basic environments. The sample exhibits exceptional OER effectiveness in a 1.0 M KOH concentration and its cubic phase was confirmed by X-ray diffraction (XRD) analysis. The fabricated composite exhibits a greater surface area, which improves catalytic performance for OER. Moreover, the CuFe2O4/PANI composite showed remarkable catalytic applications for OER in 1 M KOH, exhibited extraordinary stability (30 h) and a reduced overpotential (194 mV) to obtain the current density (j) (10 mA/cm2). In comparison to the pure CuFe2O4 nanomaterial, composite showed a minimal onset potential (1.39 V), a notable electrochemical active surface area (ECSA) of 76.25 cm2 and an amazing Tafel plot (34 mV/dec). Furthermore, the intrinsic electronic structure of CuFe2O4 significantly enhances OER kinetics, underscoring its potential as an efficient and renewable alternative to noble metal-based electrocatalysts. These results not only validate the efficacy of the synthesized CuFe2O4/PANI nanocomposite as a promising OER electrocatalyst but also pave the way for its prospective integration into future energy storage systems and large-scale renewable energy conversion technologies.
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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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