Peng Zhang , Yuyu Li , Yonggang Tong , Yongle Hu , Jie Wang , Xiubing Liang , Hao Lan , Mingjun Zhang , Cong Mao , Kaiming Wang
{"title":"硬质无裂纹tic基陶瓷的增材制造","authors":"Peng Zhang , Yuyu Li , Yonggang Tong , Yongle Hu , Jie Wang , Xiubing Liang , Hao Lan , Mingjun Zhang , Cong Mao , Kaiming Wang","doi":"10.1016/j.ceramint.2025.03.144","DOIUrl":null,"url":null,"abstract":"<div><div>Additive manufacturing of hard TiC-based cermets typically employs a high-energy beam as the energy source but suffers from high residual stress and microcracks. Herein, we propose an economical additive-manufacturing process for TiC-based cermets using powder extrusion printing (PEP) combined with pressureless sintering, which overcomes inadequacies such as extensive residual stress and microcracks. Complex cermet parts with high densities are successfully fabricated, thereby experimentally demonstrating the feasibility of this method. The as-produced TiC<sub>60</sub>(Ni<sub>88</sub>Fe<sub>12</sub>)<sub>40</sub> composites exhibit a typical core-rim structure, which plays an important role in improving the interfacial bonding ability. The sintering temperature has a significant impact on the microstructure and mechanical properties. The flexural strength and microhardness increase first and then decrease at temperatures ranging from 1390 to 1430 °C. Optimum mechanical properties are achieved at 1410 °C with flexural strength and microhardness of 1013 ± 17 MPa and 965 ± 18 HV<sub>0.2</sub>, respectively. The additive-manufactured cermets exhibit superior abrasive resistance and the main abrasive mechanism is adhesive wear accompanied by oxidative wear. The good wear resistance is attributed to the high hardness of the TiC phase and the lubricating effect of the abrasive debris.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 18","pages":"Pages 24618-24627"},"PeriodicalIF":5.6000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Additive manufacturing of hard and crack-freeTiC-based cermets\",\"authors\":\"Peng Zhang , Yuyu Li , Yonggang Tong , Yongle Hu , Jie Wang , Xiubing Liang , Hao Lan , Mingjun Zhang , Cong Mao , Kaiming Wang\",\"doi\":\"10.1016/j.ceramint.2025.03.144\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Additive manufacturing of hard TiC-based cermets typically employs a high-energy beam as the energy source but suffers from high residual stress and microcracks. Herein, we propose an economical additive-manufacturing process for TiC-based cermets using powder extrusion printing (PEP) combined with pressureless sintering, which overcomes inadequacies such as extensive residual stress and microcracks. Complex cermet parts with high densities are successfully fabricated, thereby experimentally demonstrating the feasibility of this method. The as-produced TiC<sub>60</sub>(Ni<sub>88</sub>Fe<sub>12</sub>)<sub>40</sub> composites exhibit a typical core-rim structure, which plays an important role in improving the interfacial bonding ability. The sintering temperature has a significant impact on the microstructure and mechanical properties. The flexural strength and microhardness increase first and then decrease at temperatures ranging from 1390 to 1430 °C. Optimum mechanical properties are achieved at 1410 °C with flexural strength and microhardness of 1013 ± 17 MPa and 965 ± 18 HV<sub>0.2</sub>, respectively. The additive-manufactured cermets exhibit superior abrasive resistance and the main abrasive mechanism is adhesive wear accompanied by oxidative wear. The good wear resistance is attributed to the high hardness of the TiC phase and the lubricating effect of the abrasive debris.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"51 18\",\"pages\":\"Pages 24618-24627\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2025-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884225012623\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884225012623","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Additive manufacturing of hard and crack-freeTiC-based cermets
Additive manufacturing of hard TiC-based cermets typically employs a high-energy beam as the energy source but suffers from high residual stress and microcracks. Herein, we propose an economical additive-manufacturing process for TiC-based cermets using powder extrusion printing (PEP) combined with pressureless sintering, which overcomes inadequacies such as extensive residual stress and microcracks. Complex cermet parts with high densities are successfully fabricated, thereby experimentally demonstrating the feasibility of this method. The as-produced TiC60(Ni88Fe12)40 composites exhibit a typical core-rim structure, which plays an important role in improving the interfacial bonding ability. The sintering temperature has a significant impact on the microstructure and mechanical properties. The flexural strength and microhardness increase first and then decrease at temperatures ranging from 1390 to 1430 °C. Optimum mechanical properties are achieved at 1410 °C with flexural strength and microhardness of 1013 ± 17 MPa and 965 ± 18 HV0.2, respectively. The additive-manufactured cermets exhibit superior abrasive resistance and the main abrasive mechanism is adhesive wear accompanied by oxidative wear. The good wear resistance is attributed to the high hardness of the TiC phase and the lubricating effect of the abrasive debris.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.