一种新型镍沸石-生物炭绿色催化剂:TPR、TPD和XPS研究表明其组成和制备策略优化

IF 3.9 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Suryamol Nambyaruveettil , Labeeb Ali , Mirza Belal Beg , Abbas Khaleel , Mohammednoor Altarawneh
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引用次数: 0

摘要

绿色加氢技术的发展取决于生产性能稳定、价格合理的催化剂载体。本研究合成并优化了一种新型镍沸石-生物炭混合催化剂,并通过改变其组成、合成方法和金属负载对其进行了改进。该催化剂是用商业上获得的丝光沸石沸石和高硅骨架型材料开发的,这种材料具有强酸性和热稳定性,以及通过控制热解从枣核粉末中提取的生物炭,分别具有酸性和表面氧化功能。利用程序升温还原(TPR)、程序升温解吸(TPD)和x射线光电子能谱(XPS)对材料的还原性、金属分散性、金属载体相互作用强度和电子相互作用进行了研究,从而对材料进行了全面的描述。在不同的镍负载(5%,15%,25%)中,15%被确定为最佳负载。同样,对沸石含量、浸渍顺序、湿浸渍和共浸渍对催化剂还原性的影响进行了批判性分析。镍沸石生物炭(NZB)的最佳配方具有低还原温度(Tmax = 390℃)、高耗氢量(7135.2 μmol -1)、中等金属-载体相互作用和高分散性(63.27%)等特点。与传统的Ni基催化剂(如Ni/Al2O3和Ni/SiO2)相比,该混合体系表现出更好的还原性和高金属分散性。沸石的酸性和生物炭的氧化性共同增强了体系的稳健性。在XPS测试中,Ni的2p结合能显示出正的位移,因此证实了金属和衬底之间的强电联系。这项工作提出了一个新的,环保的,灵活的催化支持系统,提高镍的分散和还原性。该研究将为其在选择性加氢等催化领域的应用提供基础。优化后的NZB体系成功应用于1,3-丁二烯选择性加氢,转化率达到100%,并具有良好的抗失活能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A novel Ni–zeolite–biochar green catalyst: optimization of composition and preparation strategy revealed by TPR, TPD, and XPS

A novel Ni–zeolite–biochar green catalyst: optimization of composition and preparation strategy revealed by TPR, TPD, and XPS
The development in green hydrogenation technology depends on the production of robust and reasonably priced catalyst supports. This study synthesized and optimized a novel Ni-zeolite-biochar hybrid catalyst, improved by changes in composition, method of synthesis, and metal loading. The catalyst was developed using commercially obtained mordenite zeolite with a high-silica framework-type material known for its strong acidity and thermal stability, and biochar derived from date pit powder through controlled pyrolysis, providing acidity and surface oxygenation functionalities, respectively. The investigation of reducibility, metal dispersion, metal support interaction strength and electronic interactions of the material was conducted using temperature-programmed reduction (TPR), temperature-programmed desorption (TPD), and X-ray photoelectron spectroscopy (XPS), thereby fully describing it. Out of different nickel loading (5 %,15 %,25 %), 15 % was identified as optimal. Similarly, the effects of zeolite content, impregnation order, and the roles of wet impregnation and co-impregnation in catalyst reducibility were critically analyzed. The best formulation of Nickel zeolite biochar (NZB) exhibited a low reduction temperature (Tmax = 390 °C), high hydrogen consumption (7135.2 μmolg-1), medium metal-support interaction, and high dispersion (63.27 %). Compared to conventional Ni-based catalysts such as Ni/Al2O3 and Ni/SiO2, the hybrid system demonstrated an improved reducibility and high metal dispersion. The robustness of the system was enhanced by the acidity of the zeolite and the oxygenation properties of the biochar together. The Ni 2p binding energy exhibited a positive shift on the XPS test, therefore confirming a strong electrical link between the metal and the substrate. This work presents a fresh, environmentally friendly, flexible catalytic support system that enhances nickel dispersion and reducibility. This study will provide the foundation for catalytic applications including selective hydrogenations. The catalytic relevance of the optimized NZB system was demonstrated through its successful application in 1,3-butadiene selective hydrogenation, achieving 100 % conversion with excellent deactivation resistance.
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来源期刊
Materials Science and Engineering: B
Materials Science and Engineering: B 工程技术-材料科学:综合
CiteScore
5.60
自引率
2.80%
发文量
481
审稿时长
3.5 months
期刊介绍: The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.
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