Mohsen Ghali, Cyril O Ugwuoke, Ahmed Abd El-Moneim
{"title":"用于高性能同结二极管的无溶剂喷涂n型PEDOT PSS薄膜。","authors":"Mohsen Ghali, Cyril O Ugwuoke, Ahmed Abd El-Moneim","doi":"10.1038/s41598-024-73971-y","DOIUrl":null,"url":null,"abstract":"<p><p>Pristine PEDOT: PSS is a p-type material with salient features. However, studies have revealed that the electrical property of pristine PEDOT: PSS can be switched to n-type by solvent treatment. Notwithstanding that this method is simple, it performs inconsistently and primarily affects the samples' surfaces due to the migration of the solvent molecules into the polymer network. These solvents are also hazardous and unfavourable to the environment. In this work, we report solvent-free switching electrical characteristics of pristine PEDOT: PSS to n-type using a spray coating technique. The obtained n-PEDOT: PSS exhibits excellent optical and electrical characteristics. In addition, high Seebeck coefficient of - 1320.06 ± 38.42 µVK<sup>-1</sup> and power factor of 4.32 ± 0.25 µWm<sup>-1</sup>K<sup>-2</sup> were found. The obtained n-PEDOT: PSS was used in the fabrication of a homojunction diode. The I-V curve showed rectification characteristics with rectification ratio and barrier height of 17.2 and 0.047 eV, respectively, which is one of the best reported values in the literature for all PEDOT: PSS-based diode.</p>","PeriodicalId":21811,"journal":{"name":"Scientific Reports","volume":"15 1","pages":"20275"},"PeriodicalIF":3.9000,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12198408/pdf/","citationCount":"0","resultStr":"{\"title\":\"Solvent free spray coated n type PEDOT PSS thin film for high performance homojunction diode.\",\"authors\":\"Mohsen Ghali, Cyril O Ugwuoke, Ahmed Abd El-Moneim\",\"doi\":\"10.1038/s41598-024-73971-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Pristine PEDOT: PSS is a p-type material with salient features. However, studies have revealed that the electrical property of pristine PEDOT: PSS can be switched to n-type by solvent treatment. Notwithstanding that this method is simple, it performs inconsistently and primarily affects the samples' surfaces due to the migration of the solvent molecules into the polymer network. These solvents are also hazardous and unfavourable to the environment. In this work, we report solvent-free switching electrical characteristics of pristine PEDOT: PSS to n-type using a spray coating technique. The obtained n-PEDOT: PSS exhibits excellent optical and electrical characteristics. In addition, high Seebeck coefficient of - 1320.06 ± 38.42 µVK<sup>-1</sup> and power factor of 4.32 ± 0.25 µWm<sup>-1</sup>K<sup>-2</sup> were found. The obtained n-PEDOT: PSS was used in the fabrication of a homojunction diode. The I-V curve showed rectification characteristics with rectification ratio and barrier height of 17.2 and 0.047 eV, respectively, which is one of the best reported values in the literature for all PEDOT: PSS-based diode.</p>\",\"PeriodicalId\":21811,\"journal\":{\"name\":\"Scientific Reports\",\"volume\":\"15 1\",\"pages\":\"20275\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12198408/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scientific Reports\",\"FirstCategoryId\":\"103\",\"ListUrlMain\":\"https://doi.org/10.1038/s41598-024-73971-y\",\"RegionNum\":2,\"RegionCategory\":\"综合性期刊\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scientific Reports","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1038/s41598-024-73971-y","RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
Solvent free spray coated n type PEDOT PSS thin film for high performance homojunction diode.
Pristine PEDOT: PSS is a p-type material with salient features. However, studies have revealed that the electrical property of pristine PEDOT: PSS can be switched to n-type by solvent treatment. Notwithstanding that this method is simple, it performs inconsistently and primarily affects the samples' surfaces due to the migration of the solvent molecules into the polymer network. These solvents are also hazardous and unfavourable to the environment. In this work, we report solvent-free switching electrical characteristics of pristine PEDOT: PSS to n-type using a spray coating technique. The obtained n-PEDOT: PSS exhibits excellent optical and electrical characteristics. In addition, high Seebeck coefficient of - 1320.06 ± 38.42 µVK-1 and power factor of 4.32 ± 0.25 µWm-1K-2 were found. The obtained n-PEDOT: PSS was used in the fabrication of a homojunction diode. The I-V curve showed rectification characteristics with rectification ratio and barrier height of 17.2 and 0.047 eV, respectively, which is one of the best reported values in the literature for all PEDOT: PSS-based diode.
期刊介绍：
We publish original research from all areas of the natural sciences, psychology, medicine and engineering. You can learn more about what we publish by browsing our specific scientific subject areas below or explore Scientific Reports by browsing all articles and collections.
Scientific Reports has a 2-year impact factor: 4.380 (2021), and is the 6th most-cited journal in the world, with more than 540,000 citations in 2020 (Clarivate Analytics, 2021).
•Engineering
Engineering covers all aspects of engineering, technology, and applied science. It plays a crucial role in the development of technologies to address some of the world''s biggest challenges, helping to save lives and improve the way we live.
•Physical sciences
Physical sciences are those academic disciplines that aim to uncover the underlying laws of nature — often written in the language of mathematics. It is a collective term for areas of study including astronomy, chemistry, materials science and physics.
•Earth and environmental sciences
Earth and environmental sciences cover all aspects of Earth and planetary science and broadly encompass solid Earth processes, surface and atmospheric dynamics, Earth system history, climate and climate change, marine and freshwater systems, and ecology. It also considers the interactions between humans and these systems.
•Biological sciences
Biological sciences encompass all the divisions of natural sciences examining various aspects of vital processes. The concept includes anatomy, physiology, cell biology, biochemistry and biophysics, and covers all organisms from microorganisms, animals to plants.
•Health sciences
The health sciences study health, disease and healthcare. This field of study aims to develop knowledge, interventions and technology for use in healthcare to improve the treatment of patients.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
