Lu Zhu, Mingxin Shi, Hanxiong Lyu, Yang Liu, Shipeng Zhang, Chi Sun Poon
{"title":"钒低碳粘结剂体系的创新两步合成设计方法","authors":"Lu Zhu, Mingxin Shi, Hanxiong Lyu, Yang Liu, Shipeng Zhang, Chi Sun Poon","doi":"10.1016/j.cemconres.2025.107977","DOIUrl":null,"url":null,"abstract":"<div><div>A novel two-step synthesis approach was developed to create a low-carbon C<sub>2</sub>S binder system incorporating vanadium, utilizing thermodynamic modeling and subsequent experimental validation. The modeling identified 1 wt% V<sub>2</sub>O<sub>5</sub> as the ideal dosage since excessive V<sub>2</sub>O<sub>5</sub> led to Ca<sub>2</sub>V<sub>2</sub>O<sub>7</sub> generation, depleting CaO in C<sub>2</sub>S phases. Additionally, 1400 °C was the optimal clinkering temperature for C<sub>2</sub>S synthesis as higher temperatures favored C<sub>3</sub>S formation while lower temperatures reduced the C<sub>2</sub>S content. Experiments confirmed that clinkering at 1400 °C could produce high <em>β</em>-C<sub>2</sub>S content in V<sub>2</sub>O<sub>5</sub>-doped binders, with V<sup>5+</sup> ions stabilizing <em>β</em>-C<sub>2</sub>S and inhibiting its transformation to <em>γ</em>-C<sub>2</sub>S. Small amounts of Ca<sub>2</sub>V<sub>2</sub>O<sub>7</sub> formation during clinkering could also promote the V<sub>2</sub>O<sub>5</sub> passivation. After 1-day carbonation, vanadium-dosed pastes prepared at 1400 °C possessed low porosity and dense morphologies, contributing to superior strength by forming CaCO<sub>3</sub> and gel phases. This approach offers a sustainable direction to maximize the performance of low-carbon binder systems by recycling heavy metal-derived solid wastes.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"197 ","pages":"Article 107977"},"PeriodicalIF":10.9000,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Innovative two-step synthesis design approach in developing vanadium incorporated low-carbon binder system\",\"authors\":\"Lu Zhu, Mingxin Shi, Hanxiong Lyu, Yang Liu, Shipeng Zhang, Chi Sun Poon\",\"doi\":\"10.1016/j.cemconres.2025.107977\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel two-step synthesis approach was developed to create a low-carbon C<sub>2</sub>S binder system incorporating vanadium, utilizing thermodynamic modeling and subsequent experimental validation. The modeling identified 1 wt% V<sub>2</sub>O<sub>5</sub> as the ideal dosage since excessive V<sub>2</sub>O<sub>5</sub> led to Ca<sub>2</sub>V<sub>2</sub>O<sub>7</sub> generation, depleting CaO in C<sub>2</sub>S phases. Additionally, 1400 °C was the optimal clinkering temperature for C<sub>2</sub>S synthesis as higher temperatures favored C<sub>3</sub>S formation while lower temperatures reduced the C<sub>2</sub>S content. Experiments confirmed that clinkering at 1400 °C could produce high <em>β</em>-C<sub>2</sub>S content in V<sub>2</sub>O<sub>5</sub>-doped binders, with V<sup>5+</sup> ions stabilizing <em>β</em>-C<sub>2</sub>S and inhibiting its transformation to <em>γ</em>-C<sub>2</sub>S. Small amounts of Ca<sub>2</sub>V<sub>2</sub>O<sub>7</sub> formation during clinkering could also promote the V<sub>2</sub>O<sub>5</sub> passivation. After 1-day carbonation, vanadium-dosed pastes prepared at 1400 °C possessed low porosity and dense morphologies, contributing to superior strength by forming CaCO<sub>3</sub> and gel phases. This approach offers a sustainable direction to maximize the performance of low-carbon binder systems by recycling heavy metal-derived solid wastes.</div></div>\",\"PeriodicalId\":266,\"journal\":{\"name\":\"Cement and Concrete Research\",\"volume\":\"197 \",\"pages\":\"Article 107977\"},\"PeriodicalIF\":10.9000,\"publicationDate\":\"2025-06-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cement and Concrete Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0008884625001966\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CONSTRUCTION & BUILDING TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cement and Concrete Research","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0008884625001966","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
Innovative two-step synthesis design approach in developing vanadium incorporated low-carbon binder system
A novel two-step synthesis approach was developed to create a low-carbon C2S binder system incorporating vanadium, utilizing thermodynamic modeling and subsequent experimental validation. The modeling identified 1 wt% V2O5 as the ideal dosage since excessive V2O5 led to Ca2V2O7 generation, depleting CaO in C2S phases. Additionally, 1400 °C was the optimal clinkering temperature for C2S synthesis as higher temperatures favored C3S formation while lower temperatures reduced the C2S content. Experiments confirmed that clinkering at 1400 °C could produce high β-C2S content in V2O5-doped binders, with V5+ ions stabilizing β-C2S and inhibiting its transformation to γ-C2S. Small amounts of Ca2V2O7 formation during clinkering could also promote the V2O5 passivation. After 1-day carbonation, vanadium-dosed pastes prepared at 1400 °C possessed low porosity and dense morphologies, contributing to superior strength by forming CaCO3 and gel phases. This approach offers a sustainable direction to maximize the performance of low-carbon binder systems by recycling heavy metal-derived solid wastes.
期刊介绍:
Cement and Concrete Research is dedicated to publishing top-notch research on the materials science and engineering of cement, cement composites, mortars, concrete, and related materials incorporating cement or other mineral binders. The journal prioritizes reporting significant findings in research on the properties and performance of cementitious materials. It also covers novel experimental techniques, the latest analytical and modeling methods, examination and diagnosis of actual cement and concrete structures, and the exploration of potential improvements in materials.