掠射角沉积纳米结构碲层防止锌离子电池阳极枝晶形成和副反应。

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nanomaterials Pub Date : 2025-06-19 DOI:10.3390/nano15120952
Salim Hussain, S M Sayem, Assem Basurrah, Tahany Rashed, Fumiya Watanabe, Noureen Siraj, Tansel Karabacak
{"title":"掠射角沉积纳米结构碲层防止锌离子电池阳极枝晶形成和副反应。","authors":"Salim Hussain, S M Sayem, Assem Basurrah, Tahany Rashed, Fumiya Watanabe, Noureen Siraj, Tansel Karabacak","doi":"10.3390/nano15120952","DOIUrl":null,"url":null,"abstract":"<p><p>Aqueous zinc ion batteries (AZIBs) have considerable potential for energy storage owing to their cost-effectiveness, safety, and environmental sustainability. However, dendrite formation, hydrogen evolution reaction (HER), and corrosion of the bare zinc (B-Zn) anode tremendously impact the performance degradation and premature failure of AZIBs. This study introduces a glancing angle deposition (GLAD) approach during the sputtering process to fabricate tellurium nanostructured (TeNS) at the zinc (Zn) anode to avoid the aforementioned issues with the B-Zn anode. Three different deposition times (5, 10, and 30 min) were used to prepare TeNS at the Zn anode. The morphology, crystallinity, composition, and wettability of the TeNSs were analyzed. The TeNSs served as hydrophilic sites and a protective layer, facilitating uniform Zn nucleation and plating while inhibiting dendrite formation and side reactions. Consequently, the symmetric cell with TeNS deposited on the Zn anode for 10 min (Te@Zn_10 min) demonstrated an enhanced cycling stability of 350 h, the lowest nucleation overpotential of 10.65 mV at a current density of 1 mA/cm<sup>2</sup>, and an areal capacity of 0.5 mAh/cm<sup>2</sup>. The observed enhancement in the cycling stability and reduction in the nucleation overpotential can be attributed to the optimal open area fraction of the TeNSs on the Zn surface, which promotes uniform Zn deposition while effectively suppressing side reactions.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 12","pages":""},"PeriodicalIF":4.4000,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12196523/pdf/","citationCount":"0","resultStr":"{\"title\":\"Glancing Angle Deposited Nanostructured Tellurium Layer Against Dendrite Formation and Side Reactions in Aqueous Zn-Ion Battery Anode.\",\"authors\":\"Salim Hussain, S M Sayem, Assem Basurrah, Tahany Rashed, Fumiya Watanabe, Noureen Siraj, Tansel Karabacak\",\"doi\":\"10.3390/nano15120952\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Aqueous zinc ion batteries (AZIBs) have considerable potential for energy storage owing to their cost-effectiveness, safety, and environmental sustainability. However, dendrite formation, hydrogen evolution reaction (HER), and corrosion of the bare zinc (B-Zn) anode tremendously impact the performance degradation and premature failure of AZIBs. This study introduces a glancing angle deposition (GLAD) approach during the sputtering process to fabricate tellurium nanostructured (TeNS) at the zinc (Zn) anode to avoid the aforementioned issues with the B-Zn anode. Three different deposition times (5, 10, and 30 min) were used to prepare TeNS at the Zn anode. The morphology, crystallinity, composition, and wettability of the TeNSs were analyzed. The TeNSs served as hydrophilic sites and a protective layer, facilitating uniform Zn nucleation and plating while inhibiting dendrite formation and side reactions. Consequently, the symmetric cell with TeNS deposited on the Zn anode for 10 min (Te@Zn_10 min) demonstrated an enhanced cycling stability of 350 h, the lowest nucleation overpotential of 10.65 mV at a current density of 1 mA/cm<sup>2</sup>, and an areal capacity of 0.5 mAh/cm<sup>2</sup>. The observed enhancement in the cycling stability and reduction in the nucleation overpotential can be attributed to the optimal open area fraction of the TeNSs on the Zn surface, which promotes uniform Zn deposition while effectively suppressing side reactions.</p>\",\"PeriodicalId\":18966,\"journal\":{\"name\":\"Nanomaterials\",\"volume\":\"15 12\",\"pages\":\"\"},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2025-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12196523/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanomaterials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.3390/nano15120952\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanomaterials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.3390/nano15120952","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

由于其成本效益、安全性和环境可持续性,水性锌离子电池(azib)具有相当大的储能潜力。然而,枝晶的形成、析氢反应(HER)和裸锌(B-Zn)阳极的腐蚀极大地影响了azib的性能下降和过早失效。本文介绍了在锌阳极溅射过程中采用掠角沉积(GLAD)方法制备碲纳米结构(TeNS)的方法,以避免B-Zn阳极的上述问题。采用3种不同的沉积时间(5、10和30 min)在Zn阳极上制备了TeNS。分析了TeNSs的形貌、结晶度、组成和润湿性。TeNSs作为亲水性位点和保护层,促进均匀的Zn成核和电镀,同时抑制枝晶的形成和副反应。结果表明,在Zn阳极上沉积10 min (Te@Zn_10 min)的对称电池具有350 h的增强循环稳定性,在电流密度为1 mA/cm2时,成核过电位最低为10.65 mV,面积容量为0.5 mAh/cm2。循环稳定性的增强和成核过电位的降低可归因于锌表面TeNSs的最佳开面积分数,这促进了锌的均匀沉积,同时有效地抑制了副反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Glancing Angle Deposited Nanostructured Tellurium Layer Against Dendrite Formation and Side Reactions in Aqueous Zn-Ion Battery Anode.

Aqueous zinc ion batteries (AZIBs) have considerable potential for energy storage owing to their cost-effectiveness, safety, and environmental sustainability. However, dendrite formation, hydrogen evolution reaction (HER), and corrosion of the bare zinc (B-Zn) anode tremendously impact the performance degradation and premature failure of AZIBs. This study introduces a glancing angle deposition (GLAD) approach during the sputtering process to fabricate tellurium nanostructured (TeNS) at the zinc (Zn) anode to avoid the aforementioned issues with the B-Zn anode. Three different deposition times (5, 10, and 30 min) were used to prepare TeNS at the Zn anode. The morphology, crystallinity, composition, and wettability of the TeNSs were analyzed. The TeNSs served as hydrophilic sites and a protective layer, facilitating uniform Zn nucleation and plating while inhibiting dendrite formation and side reactions. Consequently, the symmetric cell with TeNS deposited on the Zn anode for 10 min (Te@Zn_10 min) demonstrated an enhanced cycling stability of 350 h, the lowest nucleation overpotential of 10.65 mV at a current density of 1 mA/cm2, and an areal capacity of 0.5 mAh/cm2. The observed enhancement in the cycling stability and reduction in the nucleation overpotential can be attributed to the optimal open area fraction of the TeNSs on the Zn surface, which promotes uniform Zn deposition while effectively suppressing side reactions.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信