BiBaO3钙钛矿的溶胶-凝胶合成及结构、电学和磁性能的综合研究。

IF 5.3 3区 化学 Q1 POLYMER SCIENCE
Gels Pub Date : 2025-06-12 DOI:10.3390/gels11060450
Faouzia Tayari, Kais Iben Nassar, João Pedro Carvalho, Sílvia Soreto Teixeira, Imen Hammami, Sílvia Rodrigues Gavinho, Manuel P F Graça, Manuel Almeida Valente
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引用次数: 0

摘要

本研究通过溶胶-凝胶法成功合成了BiBaO3钙钛矿,并对其结构、微观结构、介电、电学和磁性进行了全面表征。x射线衍射(XRD)证实形成了高结晶度的单相钙钛矿结构。扫描电镜(SEM)和能量色散x射线能谱(EDX)分析表明,该材料具有均匀的晶粒形貌和元素组成,符合预期的化学计量。介电测量表现出强烈的频率依赖行为,表明电容应用的潜力。电导率显示热激活行为,表明半导体特性。磁测量显示室温下弱铁磁行为,这对于未掺杂的基于babio3的体系来说是一个不寻常的观察结果。这种磁性可能源于合成过程中引入的细微结构扭曲或成分变化。通过与已有研究的对比,发现合成路线和微观结构特征对碧宝3的多功能性能有显著影响。总的来说,结果突出了溶胶-凝胶衍生的BiBaO3作为多功能电子和磁性应用的候选材料的前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sol-Gel Synthesis and Comprehensive Study of Structural, Electrical, and Magnetic Properties of BiBaO3 Perovskite.

In this study, BiBaO3 perovskite was successfully synthesized via the sol-gel method and thoroughly characterized to evaluate its structural, microstructural, dielectric, electrical, and magnetic properties. X-ray diffraction (XRD) confirmed the formation of a single-phase perovskite structure with high crystallinity. Scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDX) revealed a uniform grain morphology and elemental composition consistent with the intended stoichiometry. Dielectric measurements exhibited strong frequency-dependent behavior, suggesting potential for capacitive applications. The electrical conductivity displayed thermally activated behavior, indicative of semiconducting characteristics. Magnetic measurements showed weak ferromagnetic behavior at room temperature, an unusual observation for undoped BaBiO3-based systems. This magnetism may stem from subtle structural distortions or compositional variations introduced during synthesis. Comparison with previously reported studies underscores the significant influence of the synthesis route and microstructural features on the multifunctional properties of BiBaO3. Overall, the results highlight the promise of sol-gel-derived BiBaO3 as a candidate for multifunctional electronic and magnetic applications.

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来源期刊
Gels
Gels POLYMER SCIENCE-
CiteScore
4.70
自引率
19.60%
发文量
707
审稿时长
11 weeks
期刊介绍: The journal Gels (ISSN 2310-2861) is an international, open access journal on physical (supramolecular) and chemical gel-based materials. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the maximum length of the papers, and full experimental details must be provided so that the results can be reproduced. Short communications, full research papers and review papers are accepted formats for the preparation of the manuscripts. Gels aims to serve as a reference journal with a focus on gel materials for researchers working in both academia and industry. Therefore, papers demonstrating practical applications of these materials are particularly welcome. Occasionally, invited contributions (i.e., original research and review articles) on emerging issues and high-tech applications of gels are published as special issues.
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