木质素对XC48碳钢的缓蚀性能及生态毒理学效应的综合评价。

IF 5.8 3区 环境科学与生态学 0 ENVIRONMENTAL SCIENCES
Mohammed Oubahou, Wafaa Zriouel, Ali Zourif, Kaouthar Elbirgui, Nadia Iounes, Mohamed El Guendouzi, Youssef Naimi
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引用次数: 0

摘要

腐蚀带来了巨大的挑战,导致经济损失和安全隐患。传统的抑制剂通常含有有害物质,引起了环境问题。研究了木质素对XC48碳钢在1m HCl中的缓蚀性能。电化学阻抗谱、动电位极化和失重测量结果表明,木质素是一种有效的混合型缓蚀剂,在500 ppm时缓蚀率达到93.03%。吸附遵循Langmuir等温线模型,表明单层覆盖,热力学数据表明物理和化学吸附机制相结合。缓蚀剂在钢表面形成保护层,抑制阳极和阴极反应。扫描电镜和光谱分析证实了这一机理。此外,用盐渍蒿进行的急性毒性试验验证了木质素的环保性,将其定位为酸性介质中碳钢的可持续缓蚀剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Comprehensive evaluation of lignin extracted from Reseda luteola L. waste: corrosion inhibition performance for XC48 carbon steel and ecotoxicological effect.

Corrosion poses significant challenges, leading to economic losses and safety hazards. Conventional inhibitors, often containing harmful substances, raise environmental concerns. This study explores the corrosion inhibition properties of lignin extracted from Reseda luteola L. waste for XC48 carbon steel in 1 M HCl. Electrochemical impedance spectroscopy, potentiodynamic polarization, and weight loss measurements reveal that lignin acts as an effective mixed-type inhibitor, achieving 93.03% inhibition efficiency at 500 ppm. Adsorption follows the Langmuir isotherm model, indicating monolayer coverage, and thermodynamic data suggest a combination of physical and chemical adsorption mechanisms. The inhibitor forms a protective layer on the steel surface, inhibiting both anodic and cathodic reactions. Scanning electron microscopy and spectroscopic analysis confirm this mechanism. Furthermore, acute toxicity tests with Artemia salina validate lignin's eco-friendly nature, positioning it as a sustainable corrosion inhibitor for carbon steel in acidic media.

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来源期刊
CiteScore
8.70
自引率
17.20%
发文量
6549
审稿时长
3.8 months
期刊介绍: Environmental Science and Pollution Research (ESPR) serves the international community in all areas of Environmental Science and related subjects with emphasis on chemical compounds. This includes: - Terrestrial Biology and Ecology - Aquatic Biology and Ecology - Atmospheric Chemistry - Environmental Microbiology/Biobased Energy Sources - Phytoremediation and Ecosystem Restoration - Environmental Analyses and Monitoring - Assessment of Risks and Interactions of Pollutants in the Environment - Conservation Biology and Sustainable Agriculture - Impact of Chemicals/Pollutants on Human and Animal Health It reports from a broad interdisciplinary outlook.
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