Paula Madariaga-Segovia , Cristina A. Villamar-Ayala , Norma Ramos , Margarita Sánchez-Domínguez , Roberto Lavín
{"title":"热解条件对榛子壳生物炭对扑热息痛、阿莫西林和三氯生吸附性能的影响","authors":"Paula Madariaga-Segovia , Cristina A. Villamar-Ayala , Norma Ramos , Margarita Sánchez-Domínguez , Roberto Lavín","doi":"10.1016/j.cscee.2025.101251","DOIUrl":null,"url":null,"abstract":"<div><div>This study optimized the production of biochar from hazelnut shells for the adsorption of paracetamol, amoxicillin, and triclosan from water. Biochar was produced under 27 conditions (temperature: 500–900 °C, time: 0.5–2 h, particle size: 150–2000 μm). Physicochemical and instrumental analyses, as well as batch adsorption tests, characterized the samples. Temperature (900 °C) is the most significant factor influencing biochar properties and adsorption performance. Adsorption data fitted well with heterogeneous isotherm models, including the Sips model and multilayer/monolayer models. The maximum adsorption capacities for paracetamol, amoxicillin, and triclosan were 19.973, 2.992, and 2.678 mg/g, respectively. Biochar-based adsorption systems with water treatment applications will be scaled.</div></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"12 ","pages":"Article 101251"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of pyrolysis conditions on the adsorbent properties of hazelnut shell biochar to remove paracetamol, amoxicillin, and triclosan\",\"authors\":\"Paula Madariaga-Segovia , Cristina A. Villamar-Ayala , Norma Ramos , Margarita Sánchez-Domínguez , Roberto Lavín\",\"doi\":\"10.1016/j.cscee.2025.101251\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study optimized the production of biochar from hazelnut shells for the adsorption of paracetamol, amoxicillin, and triclosan from water. Biochar was produced under 27 conditions (temperature: 500–900 °C, time: 0.5–2 h, particle size: 150–2000 μm). Physicochemical and instrumental analyses, as well as batch adsorption tests, characterized the samples. Temperature (900 °C) is the most significant factor influencing biochar properties and adsorption performance. Adsorption data fitted well with heterogeneous isotherm models, including the Sips model and multilayer/monolayer models. The maximum adsorption capacities for paracetamol, amoxicillin, and triclosan were 19.973, 2.992, and 2.678 mg/g, respectively. Biochar-based adsorption systems with water treatment applications will be scaled.</div></div>\",\"PeriodicalId\":34388,\"journal\":{\"name\":\"Case Studies in Chemical and Environmental Engineering\",\"volume\":\"12 \",\"pages\":\"Article 101251\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Case Studies in Chemical and Environmental Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666016425001586\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Environmental Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Case Studies in Chemical and Environmental Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666016425001586","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
Influence of pyrolysis conditions on the adsorbent properties of hazelnut shell biochar to remove paracetamol, amoxicillin, and triclosan
This study optimized the production of biochar from hazelnut shells for the adsorption of paracetamol, amoxicillin, and triclosan from water. Biochar was produced under 27 conditions (temperature: 500–900 °C, time: 0.5–2 h, particle size: 150–2000 μm). Physicochemical and instrumental analyses, as well as batch adsorption tests, characterized the samples. Temperature (900 °C) is the most significant factor influencing biochar properties and adsorption performance. Adsorption data fitted well with heterogeneous isotherm models, including the Sips model and multilayer/monolayer models. The maximum adsorption capacities for paracetamol, amoxicillin, and triclosan were 19.973, 2.992, and 2.678 mg/g, respectively. Biochar-based adsorption systems with water treatment applications will be scaled.