熔体淬火合成含锰ZIF玻璃

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-06-25 DOI:10.1039/D5CC02342D

Luis León-Alcaide, Alberto Fernández-Alarcón, Joaquín Calbo, David A. Keen and Guillermo Mínguez Espallargas

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引用次数: 0

摘要

在这项工作中，我们用第一种锰基玻璃扩展了能够熔化淬火成玻璃相的zif家族。这是通过无溶剂合成和随后的熔融制备两种新的mn基zif来实现的，它们的拓扑结构分别为di -c和zni。该研究还提供了金属对熔化和分解行为的直接比较，突出了粘结强度和热性能之间的关系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Melt-quenched synthesis of a manganese ZIF glass†

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Melt-quenched synthesis of a manganese ZIF glass†

In this work we expand the family of ZIFs capable of being melt-quenched into a vitreous phase with the first Mn-based glass. This is achieved by preparing two new Mn-based ZIFs with topologies dia-c and znivia solvent-free synthesis and subsequent melting. This study also provides a direct comparison of metal effects on melting and decomposition behaviour, highlighting the relationship between bond strength and thermal properties.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.