{"title":"Shapley加性解释揭示了气候、地形、人为活动和地球化学性质对土壤钴、镍和钒含量的影响","authors":"Zhiqiang Bai, Fangyi Li, Shirong Zhang, Ting Li, Guiyin Wang, Xiaoxun Xu, Xiaomei Pan, Qinmei Zhong, Wei Zhou, Yulin Pu, Yongxia Jia","doi":"10.1016/j.jhazmat.2025.139070","DOIUrl":null,"url":null,"abstract":"The quantification of environmental drivers for soil heavy metals is crucial for pollution control, yet their relative importance and critical thresholds remain unquantified at the macroscale. Therefore, Shapley additive explanations based on a random forest model were used to analyze environmental drivers of soil cobalt, nickel and vanadium distributions along a 4000-km transect. These results revealed that climate was the dominant factor, followed by topography, anthropogenic activities, and soil geochemical properties. Specifically, mean annual precipitation predominantly shaped the distributions of total and residual contents of these metals through weathering-leaching equilibrium (threshold approximately 670<!-- --> <!-- -->mm), while acting synergistically with mean annual temperature (exceeding 5 °C) to promote vanadium transformation from labile to residual states. Altitude enhanced organic bound nickel and vanadium accumulation via hydrothermal and organic matter regulation. Low thresholds for population density (97 people km<sup>-2</sup>) and electricity consumption (555017 kWh km<sup>-2</sup>) indicated minimal anthropogenic activities could elevate carbonate bound metals through cement-derived carbonate cycling. The attenuated latitudinal trends of heavy metals were primarily attributed to biphasic effects of environmental factors and their interactive compensation. Therefore, climate dominated but synergized with other environmental drivers to collectively shape soil cobalt, nickel and vanadium distribution patterns.","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":"8 1","pages":""},"PeriodicalIF":11.3000,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Shapley additive explanations revealed the effects of climate, topography, anthropogenic activities and geochemical properties on soil cobalt, nickel and vanadium contents\",\"authors\":\"Zhiqiang Bai, Fangyi Li, Shirong Zhang, Ting Li, Guiyin Wang, Xiaoxun Xu, Xiaomei Pan, Qinmei Zhong, Wei Zhou, Yulin Pu, Yongxia Jia\",\"doi\":\"10.1016/j.jhazmat.2025.139070\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The quantification of environmental drivers for soil heavy metals is crucial for pollution control, yet their relative importance and critical thresholds remain unquantified at the macroscale. Therefore, Shapley additive explanations based on a random forest model were used to analyze environmental drivers of soil cobalt, nickel and vanadium distributions along a 4000-km transect. These results revealed that climate was the dominant factor, followed by topography, anthropogenic activities, and soil geochemical properties. Specifically, mean annual precipitation predominantly shaped the distributions of total and residual contents of these metals through weathering-leaching equilibrium (threshold approximately 670<!-- --> <!-- -->mm), while acting synergistically with mean annual temperature (exceeding 5 °C) to promote vanadium transformation from labile to residual states. Altitude enhanced organic bound nickel and vanadium accumulation via hydrothermal and organic matter regulation. Low thresholds for population density (97 people km<sup>-2</sup>) and electricity consumption (555017 kWh km<sup>-2</sup>) indicated minimal anthropogenic activities could elevate carbonate bound metals through cement-derived carbonate cycling. The attenuated latitudinal trends of heavy metals were primarily attributed to biphasic effects of environmental factors and their interactive compensation. Therefore, climate dominated but synergized with other environmental drivers to collectively shape soil cobalt, nickel and vanadium distribution patterns.\",\"PeriodicalId\":361,\"journal\":{\"name\":\"Journal of Hazardous Materials\",\"volume\":\"8 1\",\"pages\":\"\"},\"PeriodicalIF\":11.3000,\"publicationDate\":\"2025-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Hazardous Materials\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jhazmat.2025.139070\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Hazardous Materials","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.jhazmat.2025.139070","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Shapley additive explanations revealed the effects of climate, topography, anthropogenic activities and geochemical properties on soil cobalt, nickel and vanadium contents
The quantification of environmental drivers for soil heavy metals is crucial for pollution control, yet their relative importance and critical thresholds remain unquantified at the macroscale. Therefore, Shapley additive explanations based on a random forest model were used to analyze environmental drivers of soil cobalt, nickel and vanadium distributions along a 4000-km transect. These results revealed that climate was the dominant factor, followed by topography, anthropogenic activities, and soil geochemical properties. Specifically, mean annual precipitation predominantly shaped the distributions of total and residual contents of these metals through weathering-leaching equilibrium (threshold approximately 670 mm), while acting synergistically with mean annual temperature (exceeding 5 °C) to promote vanadium transformation from labile to residual states. Altitude enhanced organic bound nickel and vanadium accumulation via hydrothermal and organic matter regulation. Low thresholds for population density (97 people km-2) and electricity consumption (555017 kWh km-2) indicated minimal anthropogenic activities could elevate carbonate bound metals through cement-derived carbonate cycling. The attenuated latitudinal trends of heavy metals were primarily attributed to biphasic effects of environmental factors and their interactive compensation. Therefore, climate dominated but synergized with other environmental drivers to collectively shape soil cobalt, nickel and vanadium distribution patterns.
期刊介绍:
The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.