钯催化硅炔与芳基磺酰氯的[2+2+2]偶联环化。

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-06-24 DOI:10.1021/acs.joc.5c00524

Yukun Li, Luo Liu, Fangsheng Huang, Huanfeng Jiang and Wei Zeng*,

引用次数: 0

摘要

研究了一种新的Pd(0)催化硅烯与磺酰芳烃的[2+2+2]偶联环化反应。该方法为获取非芳构化苯并硅环骨架分子提供了一种简明的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Pd-Catalyzed [2+2+2] Coupling-Cyclization of Sila-Enynes with Arylsulfonyl Chlorides

查看原文本刊更多论文

Pd-Catalyzed [2+2+2] Coupling-Cyclization of Sila-Enynes with Arylsulfonyl Chlorides

A novel Pd(0)-catalyzed [2+2+2] coupling-cyclization of sila-enynes with sulfonylarenes has been developed. The method provides a concise approach to access nonaromatizable benzosilacycle skeleton molecules.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.