（氢硅基）二乙基硼烷的制备及反应

IF 2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2025-05-21 DOI:10.1002/ejic.202500068

Ryota Koyanagi, Mutsuki Tanaka, Yuki Nonaka, Kyoka Mori, Shogo Morisako, Yohsuke Yamamoto, Atsushi Kawachi

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引用次数: 0

摘要

（氢二烷基硅基）三甲基锡烷(3)与n-BuLi通过Sn-Li交换制备（氢二烷基硅基）锂(2)，并与氯硅烷和氟二烷基硼烷反应，分别生成氢二硅烷4-7和氢硅基硼烷1。氢硅硼烷1被分离为黄色晶体，并使用核磁共振光谱、紫外-可见光谱、荧光光谱和x射线晶体学对其进行了表征。氢硅硼烷1的DFT计算及其结构数据揭示了其独特的Si - H和Si - B键特征。最后，研究了氢硅硼烷1与醇、烷基锂等亲核试剂的反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Preparation and Reactions of (Hydrosilyl)diarylborane

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Preparation and Reactions of (Hydrosilyl)diarylborane

(Hydrodimesitysilyl)lithium (2) is prepared via the Sn–Li exchange of (hydrodimesitylsilyl)trimethylstannane (3) with n-BuLi and it reacts with chlorosilanes and fluorodimesitylborane to afford hydrodisilanes 4–7 and hydrosilylborane 1, respectively. Hydrosilylborane 1 is isolated as yellow crystals and characterized using NMR spectroscopy, UV–vis spectroscopy, fluorescence spectroscopy, and X-ray crystallography. DFT calculations of hydrosilylborane 1 and its structural data reveal unique SiH and SiB bond characteristics. Finally, the reactions of hydrosilylborane 1 with nucleophiles, such as alcohols and alkyllithiums, are investigated.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.