{"title":"新型Z-scheme BiOCl/g-C3N4纳米复合材料的高效光催化降解有机污染物及载流子动力学研究","authors":"Orawan Rojviroon , Gomathi Abimannan , Priyadharsan Arumugam , Maadeswaran Palanisamy , Ranjith Rajendran , Govarthini Ramasamy , Sanya Sirivithayapakorn , Natacha Phetyim , Thammasak Rojviroon","doi":"10.1016/j.enmm.2025.101086","DOIUrl":null,"url":null,"abstract":"<div><div>In this research work, Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C<sub>3</sub>N<sub>4</sub> materials. The photocatalytic degradation efficacy of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"24 ","pages":"Article 101086"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Z-scheme BiOCl/g-C3N4 nanocomposite for high performance photocatalytic degradation of organic pollutants and charge carrier dynamics\",\"authors\":\"Orawan Rojviroon , Gomathi Abimannan , Priyadharsan Arumugam , Maadeswaran Palanisamy , Ranjith Rajendran , Govarthini Ramasamy , Sanya Sirivithayapakorn , Natacha Phetyim , Thammasak Rojviroon\",\"doi\":\"10.1016/j.enmm.2025.101086\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this research work, Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C<sub>3</sub>N<sub>4</sub> materials. The photocatalytic degradation efficacy of BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C<sub>3</sub>N<sub>4</sub> nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.</div></div>\",\"PeriodicalId\":11716,\"journal\":{\"name\":\"Environmental Nanotechnology, Monitoring and Management\",\"volume\":\"24 \",\"pages\":\"Article 101086\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Nanotechnology, Monitoring and Management\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2215153225000479\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Environmental Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Nanotechnology, Monitoring and Management","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2215153225000479","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
Novel Z-scheme BiOCl/g-C3N4 nanocomposite for high performance photocatalytic degradation of organic pollutants and charge carrier dynamics
In this research work, Z scheme BiOCl/g-C3N4 nanocomposite was synthesized through hydrothermal process and combined with thermal decomposition method. Numerous characterization techniques were utilized to examine the phase structure, functional groups, morphology, elemental composition, electronic structure and optical behaviour of as synthesized materials. The boosted light absorption capability of BiOCl/g-C3N4 nanocomposite which is accredited to the synergetic interaction between the BiOCl and g-C3N4 materials. The photocatalytic degradation efficacy of BiOCl/g-C3N4 nanocomposite over Rhodamine B (RhB) textile pollutant was exhibited 97 % within 100 min which is higher than the pristine BiOCl material. It’s caused by the active separation, allocation of electrons and holes and reduce the recombination. Five successive recycle process proved the stability and reusability of the material. Finally, This work demonstrates an enriched Z scheme BiOCl/g-C3N4 nanocomposite will deliver the impression of construct the Z scheme heterojunction photocatalyst to augment the photocatalytic activity in the occurrence of visible light.
期刊介绍:
Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation