提高4.6 V lrmo固态锂金属电池界面兼容性的双分量调制策略

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-06-23 DOI:10.1039/D5CC01807B

Mengya Wang, Linghong Xu, Jilin Tang, Hangjun Ying, Gaorong Han and Yong Shi

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引用次数: 0

摘要

具有富锂锰氧化物（LRMO）阴极的固态锂金属电池在界面兼容性方面面临挑战。本研究通过双组分调制改善了聚氯乙烯凝胶电解质与电极之间的界面。优化后的电解质具有较高的氧化稳定性，有利于形成富无机界面相，有利于界面的长期稳定性。因此，4.6 V Li|LRMO电池在0.2℃下稳定工作100次，初始容量为215.2 mAh/g，平均库仑效率为99.55%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Dual-component modulation strategy for enhancing interfacial compatibility in 4.6 V LRMO-based solid-state lithium metal batteries†

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Dual-component modulation strategy for enhancing interfacial compatibility in 4.6 V LRMO-based solid-state lithium metal batteries†

Solid-state lithium metal batteries with a Li-rich manganese oxide (LRMO) cathode suffer from challenges in interfacial compatibility. This study improves the interface between a PVC-based gel electrolyte and electrodes via dual-component modulation. The optimized electrolyte exhibits high oxidation stability and facilitates the formation of inorganic-rich interphases, contributing to the long-term stability of the interface. Therefore, the 4.6 V Li|LRMO cells operate stably for 100 cycles at 0.2C, delivering an initial capacity of 215.2 mA h g⁻¹ and average coulombic efficiency of 99.55%.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.