间歇处理法制备钛电沉积过程中薄膜生长的动力学研究。

IF 2.5 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemistryOpen Pub Date : 2025-06-20 DOI:10.1002/open.202500311

Katarzyna Grubel, Diana B Horangic, Steven Livers, Christopher J Chancellor, Riah Burnett, Bailey Byrd, Bethany Lawler, Christina Arendt, Lance R Hubbard

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引用次数: 0

摘要

由于使用以前开发的方法获得的薄膜质量差，钛电沉积作为一种技术进步已经遥不可及。本研究表明，在深共晶溶剂乙炔中电沉积Ti是可能的和可行的。此外，本研究通过批量分析表明，这种沉积具有温度依赖性，在适度加热时改变膜沉积动力学。这一紫外可见光谱研究表明，在高温下，Ti4+更容易还原为Ti3+，然后再还原为Ti2+。了解电沉积的潜在动力学为这种重要金属的应用开辟了新的场所。

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Kinetic Investigation by Batch Processing of Film Growth during the Electrodeposition of Titanium from Ethaline.

Titanium electrodeposition as a technological advance has been out of reach due to the poor film quality obtained when using previously developed methods. This study shows that the electrodeposition of Ti is possible and feasible from the deep eutectic solvent ethaline. Moreover, this study shows through batch analysis that this deposition has temperature-dependent aspects that alter the film deposition kinetics upon modest heating. This ultraviolet-visible spectroscopic study is highlighting the more facile reduction of Ti⁴⁺ to Ti³⁺ and then to Ti²⁺ at elevated temperatures. Understanding the underlying kinetics of electrodeposition opens up new venues for the application of this important metal.

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来源期刊

ChemistryOpen CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.80

自引率

4.30%

发文量

143

审稿时长

1 months

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