电化学原位合成聚4,4′-亚甲苯胺/氧化石墨烯复合材料作为硫代苯甲醚敏感和选择性传感器

IF 4.2 Q2 CHEMISTRY, MULTIDISCIPLINARY
Esmail Mohseni , Abdolrasoul Rahmani , Ali Kazemi , Zahra Hamdi
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引用次数: 0

摘要

石油和石油产品中存在的具有不良性质的硫化合物已成为全球关注的问题,促使科学家们对这些化合物的识别和去除进行研究。方法建立了基于聚4.4′-亚甲苯胺/氧化石墨烯电极(PMDA/GO)的硫代苯甲醚灵敏选择性检测伏安传感器。采用原位法进行了聚合物复合材料的电合成。聚合物合成中未使用交联剂。PMDA/GO与硫代苯甲醚之间的π-π堆积效应等非共价键作用使得印迹聚合物和印迹位点紧密。采用场发射扫描电镜、紫外可见光谱、热重分析、差示热分析和差示扫描量热法对聚(4.4′-亚甲苯胺)/氧化石墨烯进行了表征。通过循环伏安法还发现,聚PMDA/GO作为分子印迹聚合物(MIP)电极对硫代茴香醇具有良好的特异性检测。得到的MIP电极的循环伏安图显示在~ 1.5 V处有一个不可逆的阳极峰。在50 ~ 200 mg L−1浓度范围内,方波阴极电流与硫硝唑呈线性关系,相关系数(R2)为0.979,检测限(LOD)为7 mg L−1,定量限(LOQ)为26 mg L−1。所提出的硫代茴香醚检测方法表明,与非印迹聚合物(NIP)相比,印迹传感器对硫代茴香醚的灵敏度有所提高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrochemical synthesis of poly 4, 4′-methylenedianiline /graphene oxide composite by in situ method as sensitive and selective sensor of thioanisole

Electrochemical synthesis of poly 4, 4′-methylenedianiline /graphene oxide composite by in situ method as sensitive and selective sensor of thioanisole

Background

Sulfur compounds with undesirable properties present in oil and petroleum products have become a global concern, prompting scientists to conduct research into the identification and removal of these compounds.

Methods

A voltammetric sensor based on a poly4.4′-methylenedianiline /graphene oxide electrode (PMDA/GO) has been developed for the sensitive and selective detection of thioanisole. The electrosynthesis of the polymer composite was performed by in situ method. No crosslinker was used for polymer synthesis. Non-covalent bonding such as π-π stacking effect between PMDA/GO and thioanisole, made the compact imprinted polymer and imprinted sites.Poly (4.4′-methylenedianiline)/graphene oxide were characterized by Field emission scanning electron microscopy, UV–Vis spectroscopy, Thermogravimetric analysis, Differential thermal analysis and differential scanning calorimetry. By Cyclic voltammetry was also found that the poly PMDA/GO exhibit good specific detection of thioanisol when used as molecular imprinted polymer (MIP) electrodes.

Significant findings

The obtained cyclic voltammograms of the MIP electrode showed one irreversible anodic peak at ∼1.5 V. The square wave cathodic current exhibits a linear response to thioanisol over a concentration range of 50(mg L−1) to 200(mg L−1) with a correlation coefficient (R2) of 0.979, a detection limit (LOD) 7 mg L−1 and a quantification limit (LOQ) 26 mg L−1. The proposed method for thioanisole detection shows that the imprinted sensor exhibits improved sensitivity to thioanisole compared to a non-imprinted polymer (NIP).
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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