石墨烯和碳纳米管的自由基脱羧共价功能化。

IF 8.2 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

ACS Applied Materials & Interfaces Pub Date : 2025-06-18 DOI:10.1021/acsami.5c04671

Ashleigh L. Farnsworth, Yvonne Hora, Ruoxin Wang, Chima Anyaegbu, Bhagya Dharmasiri, Luke C. Henderson and Joel F. Hooper*,

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引用次数: 0

摘要

我们已经证明羧酸或氧化还原活性酯的自由基脱羧是石墨烯和碳纳米管共价修饰的一种简单有效的策略。本文描述了两种互补的方法，分别利用氧化或还原条件从羧酸或氧化还原活性酯中产生自由基。我们已经将这些方法应用于小分子、复杂药物分子和聚合物与石墨烯和碳纳米管的偶联。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation

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Covalent Functionalization of Graphene and Carbon Nanotubes by Radical Decarboxylation

We have demonstrated that the radical decarboxylation of carboxylic acids or redox-active esters is a simple and effective strategy for the covalent modification of graphene and carbon nanotubes. Two complementary methods are described in this paper, utilizing oxidative or reductive conditions to generate radicals from carboxylic acids or redox-active esters, respectively. We have applied these methods to the conjugation of small molecules, a complex drug molecule, and polymers to graphene and carbon nanotubes.

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来源期刊

ACS Applied Materials & Interfaces 工程技术-材料科学：综合

CiteScore

16.00

自引率

6.30%

发文量

4978

审稿时长

1.8 months

期刊介绍： ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.