{"title":"用铋基纳米结构反应器促进小分子还原。","authors":"Yue Wu, Bozhao Zhang, Yuan Yu, Qinyu Jiang, Shanru Feng, Yongjin Lin, Yaqiang Li, Chuhao Liu, Chen Chen","doi":"10.1039/d5cc02478a","DOIUrl":null,"url":null,"abstract":"<p><p>In this study, we encapsulated Bi in hollow carbon spheres to form a nanoreactor. It shows good activation ability for CO<sub>2</sub> and NO<sub>3</sub><sup>-</sup>, and significantly enhances the coupling of C-N intermediates. This improves urea selectivity by 66% compared to unencapsulated Bi-based catalysts and shows good stability.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Boosting small-molecule reduction with bismuth-based nanostructured reactors.\",\"authors\":\"Yue Wu, Bozhao Zhang, Yuan Yu, Qinyu Jiang, Shanru Feng, Yongjin Lin, Yaqiang Li, Chuhao Liu, Chen Chen\",\"doi\":\"10.1039/d5cc02478a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In this study, we encapsulated Bi in hollow carbon spheres to form a nanoreactor. It shows good activation ability for CO<sub>2</sub> and NO<sub>3</sub><sup>-</sup>, and significantly enhances the coupling of C-N intermediates. This improves urea selectivity by 66% compared to unencapsulated Bi-based catalysts and shows good stability.</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc02478a\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc02478a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Boosting small-molecule reduction with bismuth-based nanostructured reactors.
In this study, we encapsulated Bi in hollow carbon spheres to form a nanoreactor. It shows good activation ability for CO2 and NO3-, and significantly enhances the coupling of C-N intermediates. This improves urea selectivity by 66% compared to unencapsulated Bi-based catalysts and shows good stability.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.