Yanyu Chen , Shoujuan Wang , Guichun Hu , Fangong Kong , Jinguang Hu
{"title":"纳米银/碱性木质素/再生纤维素纤维织物的防紫外线和抗菌性能","authors":"Yanyu Chen , Shoujuan Wang , Guichun Hu , Fangong Kong , Jinguang Hu","doi":"10.1016/j.indcrop.2025.121366","DOIUrl":null,"url":null,"abstract":"<div><div>Regenerated cellulose fibers (e.g., viscose, modal) and natural cotton fibers remain dominant in summer textile production owing to their inherent softness, breathability, and moisture absorption. Nevertheless, their limited ultraviolet (UV) resistance and proneness to microbial colonization restrict extended applications. To address these limitations, we developed a novel regenerated cellulose-based composite fiber incorporating silver nanoparticles (AgNPs) and alkaline lignin (AL) through a wet-spinning approach. The synthesis process involved dissolving AL and cotton cellulose (CC) in an N,N-dimethylacetamide/lithium chloride (DMAc/LiCl) solution, followed by wet spinning to produce AL/CC fibers. Subsequently, AgNPs were in situ synthesized on the surface of the AL/CC-g fibers, resulting in Ag/AL/CC-g fibers. The structural, chemical composition, and thermal stability of the Ag/AL/CC-g fibers were characterized through XPS, SEM, DSC, TG. The Ag/AL/CC-g fibers exhibited good antibacterial activity, achieving a > 99.99 % reduction rate against both E.coli and S.aureus. The UV-blocking capability of Ag/AL/CC-g fabric (woven from Ag/AL/CC-g fibers) was evaluated, revealing a direct correlation between AL content and UV absorption. Notably, the Ag/AL/CC-g fabric(with 46 % AL and 7 % AgNPs) demonstrated “excllent” UV protection, achieving a UPF value exceeding 40, according to the European standard(EN 13758–2).This study presents a novel and effective approach to fabricating cellulose-based textiles with dual functionality—enhanced UV resistance and robust antibacterial properties—expanding their potential applications in high-performance summer apparel and medical textiles.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":"233 ","pages":"Article 121366"},"PeriodicalIF":6.2000,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ultraviolet protection and antibacterial properties of textile fabric made of silver nanoparticles/alkaline lignin/regenerated cellulose fiber\",\"authors\":\"Yanyu Chen , Shoujuan Wang , Guichun Hu , Fangong Kong , Jinguang Hu\",\"doi\":\"10.1016/j.indcrop.2025.121366\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Regenerated cellulose fibers (e.g., viscose, modal) and natural cotton fibers remain dominant in summer textile production owing to their inherent softness, breathability, and moisture absorption. Nevertheless, their limited ultraviolet (UV) resistance and proneness to microbial colonization restrict extended applications. To address these limitations, we developed a novel regenerated cellulose-based composite fiber incorporating silver nanoparticles (AgNPs) and alkaline lignin (AL) through a wet-spinning approach. The synthesis process involved dissolving AL and cotton cellulose (CC) in an N,N-dimethylacetamide/lithium chloride (DMAc/LiCl) solution, followed by wet spinning to produce AL/CC fibers. Subsequently, AgNPs were in situ synthesized on the surface of the AL/CC-g fibers, resulting in Ag/AL/CC-g fibers. The structural, chemical composition, and thermal stability of the Ag/AL/CC-g fibers were characterized through XPS, SEM, DSC, TG. The Ag/AL/CC-g fibers exhibited good antibacterial activity, achieving a > 99.99 % reduction rate against both E.coli and S.aureus. The UV-blocking capability of Ag/AL/CC-g fabric (woven from Ag/AL/CC-g fibers) was evaluated, revealing a direct correlation between AL content and UV absorption. Notably, the Ag/AL/CC-g fabric(with 46 % AL and 7 % AgNPs) demonstrated “excllent” UV protection, achieving a UPF value exceeding 40, according to the European standard(EN 13758–2).This study presents a novel and effective approach to fabricating cellulose-based textiles with dual functionality—enhanced UV resistance and robust antibacterial properties—expanding their potential applications in high-performance summer apparel and medical textiles.</div></div>\",\"PeriodicalId\":13581,\"journal\":{\"name\":\"Industrial Crops and Products\",\"volume\":\"233 \",\"pages\":\"Article 121366\"},\"PeriodicalIF\":6.2000,\"publicationDate\":\"2025-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial Crops and Products\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0926669025009124\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial Crops and Products","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926669025009124","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
Ultraviolet protection and antibacterial properties of textile fabric made of silver nanoparticles/alkaline lignin/regenerated cellulose fiber
Regenerated cellulose fibers (e.g., viscose, modal) and natural cotton fibers remain dominant in summer textile production owing to their inherent softness, breathability, and moisture absorption. Nevertheless, their limited ultraviolet (UV) resistance and proneness to microbial colonization restrict extended applications. To address these limitations, we developed a novel regenerated cellulose-based composite fiber incorporating silver nanoparticles (AgNPs) and alkaline lignin (AL) through a wet-spinning approach. The synthesis process involved dissolving AL and cotton cellulose (CC) in an N,N-dimethylacetamide/lithium chloride (DMAc/LiCl) solution, followed by wet spinning to produce AL/CC fibers. Subsequently, AgNPs were in situ synthesized on the surface of the AL/CC-g fibers, resulting in Ag/AL/CC-g fibers. The structural, chemical composition, and thermal stability of the Ag/AL/CC-g fibers were characterized through XPS, SEM, DSC, TG. The Ag/AL/CC-g fibers exhibited good antibacterial activity, achieving a > 99.99 % reduction rate against both E.coli and S.aureus. The UV-blocking capability of Ag/AL/CC-g fabric (woven from Ag/AL/CC-g fibers) was evaluated, revealing a direct correlation between AL content and UV absorption. Notably, the Ag/AL/CC-g fabric(with 46 % AL and 7 % AgNPs) demonstrated “excllent” UV protection, achieving a UPF value exceeding 40, according to the European standard(EN 13758–2).This study presents a novel and effective approach to fabricating cellulose-based textiles with dual functionality—enhanced UV resistance and robust antibacterial properties—expanding their potential applications in high-performance summer apparel and medical textiles.
期刊介绍:
Industrial Crops and Products is an International Journal publishing academic and industrial research on industrial (defined as non-food/non-feed) crops and products. Papers concern both crop-oriented and bio-based materials from crops-oriented research, and should be of interest to an international audience, hypothesis driven, and where comparisons are made statistics performed.