Xueyuan Li , Yaru Du , Niqian Du , Shanshan Du , Tianxiao Liu , Kaikai Liu , Zhiyong Liu
{"title":"通过在高效钙钛矿光伏电池中添加天然抗氧化剂来提高其抗紫外线性能","authors":"Xueyuan Li , Yaru Du , Niqian Du , Shanshan Du , Tianxiao Liu , Kaikai Liu , Zhiyong Liu","doi":"10.1016/j.cap.2025.05.014","DOIUrl":null,"url":null,"abstract":"<div><div>Perovskite solar cells (PSCs) have attracted much attention due to their excellent photoelectric properties. However, the instability of perovskites limits its development, which resulted by degradation derived from oxygen and ultraviolet light. Herein, the contain conjugated double bonds and natural antioxidant layer provided by β-carotene and astaxanthin could constitute ligand bonds with Pb<sup>2+</sup> in the form of Lewis acid-base interactions and eliminate UV-induced free radicals during photoaging process, which passivate the surface defects and improve the crystal quality of perovskite films, improving operational stability of PSCs. The optimized PSCs arrive a champion power conversion efficiency (PCE) of 23.56 %, maintaining 88 % of the original PCE after continuous operating 140 h under UV illumination state and 89 % of the original PCE after 2400 h of operation in air environment condition. This work provides a general strategy for improving the stability of PSCs.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 123-130"},"PeriodicalIF":3.1000,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improved ultraviolet resistant through the natural antioxidants in efficient perovskite photovoltaics\",\"authors\":\"Xueyuan Li , Yaru Du , Niqian Du , Shanshan Du , Tianxiao Liu , Kaikai Liu , Zhiyong Liu\",\"doi\":\"10.1016/j.cap.2025.05.014\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Perovskite solar cells (PSCs) have attracted much attention due to their excellent photoelectric properties. However, the instability of perovskites limits its development, which resulted by degradation derived from oxygen and ultraviolet light. Herein, the contain conjugated double bonds and natural antioxidant layer provided by β-carotene and astaxanthin could constitute ligand bonds with Pb<sup>2+</sup> in the form of Lewis acid-base interactions and eliminate UV-induced free radicals during photoaging process, which passivate the surface defects and improve the crystal quality of perovskite films, improving operational stability of PSCs. The optimized PSCs arrive a champion power conversion efficiency (PCE) of 23.56 %, maintaining 88 % of the original PCE after continuous operating 140 h under UV illumination state and 89 % of the original PCE after 2400 h of operation in air environment condition. This work provides a general strategy for improving the stability of PSCs.</div></div>\",\"PeriodicalId\":11037,\"journal\":{\"name\":\"Current Applied Physics\",\"volume\":\"77 \",\"pages\":\"Pages 123-130\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-06-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Applied Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1567173925001129\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Applied Physics","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1567173925001129","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Improved ultraviolet resistant through the natural antioxidants in efficient perovskite photovoltaics
Perovskite solar cells (PSCs) have attracted much attention due to their excellent photoelectric properties. However, the instability of perovskites limits its development, which resulted by degradation derived from oxygen and ultraviolet light. Herein, the contain conjugated double bonds and natural antioxidant layer provided by β-carotene and astaxanthin could constitute ligand bonds with Pb2+ in the form of Lewis acid-base interactions and eliminate UV-induced free radicals during photoaging process, which passivate the surface defects and improve the crystal quality of perovskite films, improving operational stability of PSCs. The optimized PSCs arrive a champion power conversion efficiency (PCE) of 23.56 %, maintaining 88 % of the original PCE after continuous operating 140 h under UV illumination state and 89 % of the original PCE after 2400 h of operation in air environment condition. This work provides a general strategy for improving the stability of PSCs.
期刊介绍:
Current Applied Physics (Curr. Appl. Phys.) is a monthly published international journal covering all the fields of applied science investigating the physics of the advanced materials for future applications.
Other areas covered: Experimental and theoretical aspects of advanced materials and devices dealing with synthesis or structural chemistry, physical and electronic properties, photonics, engineering applications, and uniquely pertinent measurement or analytical techniques.
Current Applied Physics, published since 2001, covers physics, chemistry and materials science, including bio-materials, with their engineering aspects. It is a truly interdisciplinary journal opening a forum for scientists of all related fields, a unique point of the journal discriminating it from other worldwide and/or Pacific Rim applied physics journals.
Regular research papers, letters and review articles with contents meeting the scope of the journal will be considered for publication after peer review.
The Journal is owned by the Korean Physical Society.